The Landau–Zener formula is an analytic solution to the equations of motion governing the transition dynamics of a 2-level quantum mechanical system, with a time-dependent Hamiltonian varying such that the energy separation of the two states is a linear function of time. The formula, giving the probability of a diabatic (not adiabatic) transition between the two energy states, was published separately by Lev Landau, Clarence Zener, Ernst Stueckelberg, and Ettore Majorana, in 1932.
Contents
- LandauZener approximation
- The LandauZener formula
- Multistate LandauZener problem
- Noise in the LandauZener problem
- References
If the system starts, in the infinite past, in the lower energy eigenstate, we wish to calculate the probability of finding the system in the upper energy eigenstate in the infinite future (a so-called Landau–Zener transition). For infinitely slow variation of the energy difference (that is, a Landau–Zener velocity of zero), the adiabatic theorem tells us that no such transition will take place, as the system will always be in an instantaneous eigenstate of the Hamiltonian at that moment in time. At non-zero velocities, transitions occur with probability as described by the Landau–Zener formula.
Landau–Zener approximation
Such transitions occur between states of the entire system, hence any description of the system must include all external influences, including collisions and external electric and magnetic fields. In order that the equations of motion for the system might be solved analytically, a set of simplifications are made, known collectively as the Landau–Zener approximation. The simplifications are as follows:
- The perturbation parameter in the Hamiltonian is a known, linear function of time
- The energy separation of the diabatic states varies linearly with time
- The coupling in the diabatic Hamiltonian matrix is independent of time
The first simplification makes this a semi-classical treatment. In the case of an atom in a magnetic field, the field strength becomes a classical variable which can be precisely measured during the transition. This requirement is quite restrictive as a linear change will not, in general, be the optimal profile to achieve the desired transition probability.
The second simplification allows us to make the substitution
where
The final simplification requires that the time–dependent perturbation does not couple the diabatic states; rather, the coupling must be due to a static deviation from a
The Landau–Zener formula
The details of Zener's solution are somewhat opaque, relying on a set of substitutions to put the equation of motion into the form of the Weber equation and using the known solution. A more transparent solution is provided by Wittig using contour integration.
The key figure of merit in this approach is the Landau–Zener velocity:
where
Using the Landau–Zener formula the probability,
The quantity
Multistate Landau–Zener problem
The simplest generalization of the two-state Landau–Zener model is a multistate system with the Hamiltonian of the form H(t)=A+Bt, where A and B are Hermitian NxN matrices with constant elements. The goal of the multistate Landau-Zener theory is to determine elements of the scattering matrix and transition probabilities between states of this model after evolution with such a Hamiltonian from negative infinite to positive infinite time. Transition probabilities are absolute value squared of scattering matrix elements.
There are exact formulas, called hierarchy constraints, that provide analytical expressions for special elements of the scattering matrix in any multi-state Landau-Zener model. Special cases of these relations are known as the Brundobler–Elser (BE) formula (noticed by Brundobler and Elser in numerical simulations and rigorously proved by Dobrescu and Sinitsyn, following the contribution of Volkov and Ostrovsky), and the no-go theorem (formulated by Sinitsyn and rigorously proved by Volkov and Ostrovsky). Discrete symmetries also often lead to constraints that reduce the number of independent elements of the scattering matrix.
There are specific integrability conditions that, when satisfied, lead to exact expressions for the scattering matrices of multistate Landau-Zener models. So, numerous completely solvable multistate Landau–Zener models have been identified and studied, including:
Noise in the Landau–Zener problem
Applications of the Landau–Zener solution to the problems of quantum state preparation and manipulation with discrete degrees of freedom stimulated the study of noise and decoherence effects on the transition probability in a driven two-state system. Several compact analytical results have been derived to describe these effects, including the Kayanuma formula for a strong diagonal noise, and Pokrovsky–Sinitsyn formula for the coupling to a fast colored noise with off-diagonal components. The effects of nuclear spin bath and heat bath coupling on the Landau–Zener process were explored by Sinitsyn and Prokof'ev and Pokrovsky and Sun, respectively.
Exact results in multistate Landau–Zener theory (no-go theorem and BE-formula) can be applied to Landau-Zener systems which are coupled to baths composed of infinite many oscillators and/or spin baths (dissipative Landau-Zener transitions). They provide exact expressions for transition probabilities averaged over final bath states if the evolution begins from the ground state at zero temperature, see in Ref. for oscillator baths and for universal results including spin baths in Ref.