Opal

Precious opal

Precious opal shows a variable interplay of internal colors, and though it is a mineraloid, it has an internal structure. At microscopic scales, precious opal is composed of silica spheres some 150 to 300 nm in diameter in a hexagonal or cubic close-packed lattice. It was shown by J. V. Sanders in the mid-1960s, that these ordered silica spheres produce the internal colors by causing the interference and diffraction of light passing through the microstructure of the opal. The regularity of the sizes and the packing of these spheres determines the quality of precious opal. Where the distance between the regularly packed planes of spheres is around half the wavelength of a component of visible light, the light of that wavelength may be subject to diffraction from the grating created by the stacked planes. The colors that are observed are determined by the spacing between the planes and the orientation of planes with respect to the incident light. The process can be described by Bragg's law of diffraction.

Visible light of diffracted wavelengths cannot pass through large thicknesses of the opal. This is the basis of the optical band gap in a photonic crystal. The notion that opals are photonic crystals for visible light was expressed in 1995 by Vasily Astratov's group. In addition, microfractures may be filled with secondary silica and form thin lamellae inside the opal during solidification. The term opalescence is commonly and erroneously used to describe this unique and beautiful phenomenon, which is correctly termed play of color. Contrarily, opalescence is correctly applied to the milky, turbid appearance of common or potch opal. Potch does not show a play of color.

For gemstone use, most opal is cut and polished to form a cabochon. "Solid" opal refers to polished stones consisting wholly of precious opal. Opals too thin to produce a "solid" may be combined with other materials to form attractive gems. An opal doublet consists of a relatively thin layer of precious opal, backed by a layer of dark-colored material, most commonly ironstone, dark or black common opal (potch), onyx, or obsidian. The darker backing emphasizes the play of color, and results in a more attractive display than a lighter potch. An opal triplet is similar to a doublet, but has a third layer, a domed cap of clear quartz or plastic on the top. The cap takes a high polish and acts as a protective layer for the opal. The top layer also acts as a magnifier, to emphasize the play of color of the opal beneath, which is often of lower quality. Triplet opals therefore have a more artificial appearance, and are not classed as precious opal. Jewelry applications of precious opal can be somewhat limited by opal's sensitivity to heat due primarily to its relatively high water content and predisposition to scratching. Combined with modern techniques of polishing, doublet opal produces a similar effect to black or boulder opal at a fraction of the price. Doublet opal also has the added benefit of having genuine opal as the top visible and touchable layer, unlike triplet opals.

Common opal

Besides the gemstone varieties that show a play of color, the other kinds of common opal include the milk opal, milky bluish to greenish (which can sometimes be of gemstone quality); resin opal, which is honey-yellow with a resinous luster; wood opal, which is caused by the replacement of the organic material in wood with opal; menilite, which is brown or grey; hyalite, a colorless glass-clear opal sometimes called Muller's glass; geyserite, also called siliceous sinter, deposited around hot springs or geysers; and diatomite or diatomaceous earth, the accumulations of diatom shells or tests.

Other varieties of opal

Fire opal is a transparent to translucent opal, with warm body colors of yellow to orange to red. Although it does not usually show any play of color, occasionally a stone will exhibit bright green flashes. The most famous source of fire opals is the state of Querétaro in Mexico; these opals are commonly called Mexican fire opals. Fire opals that do not show play of color are sometimes referred to as jelly opals. Mexican opals are sometimes cut in their rhyolitic host material if it is hard enough to allow cutting and polishing. This type of Mexican opal is referred to as a Cantera opal. Also, a type of opal from Mexico, referred to as Mexican water opal, is a colorless opal which exhibits either a bluish or golden internal sheen.

Girasol opal is a term sometimes mistakenly and improperly used to refer to fire opals, as well as a type of transparent to semitransparent type milky quartz from Madagascar which displays an asterism, or star effect, when cut properly. However, the true girasol opal is a type of hyalite opal that exhibits a bluish glow or sheen that follows the light source around. It is not a play of color as seen in precious opal, but rather an effect from microscopic inclusions. It is also sometimes referred to as water opal, too, when it is from Mexico. The two most notable locations of this type of opal are Oregon and Mexico.

Peruvian opal (also called blue opal) is a semiopaque to opaque blue-green stone found in Peru, which is often cut to include the matrix in the more opaque stones. It does not display play of color. Blue opal also comes from Oregon in the Owyhee region, as well as from Nevada around the Virgin Valley.

Synthetic opal

Opals of all varieties have been synthesized experimentally and commercially. The discovery of the ordered sphere structure of precious opal led to its synthesis by Pierre Gilson in 1974. The resulting material is distinguishable from natural opal by its regularity; under magnification, the patches of color are seen to be arranged in a "lizard skin" or "chicken wire" pattern. Furthermore, synthetic opals do not fluoresce under ultraviolet light. Synthetics are also generally lower in density and are often highly porous.

Two notable producers of synthetic opal are Kyocera and Inamori of Japan. Most so-called synthetics, however, are more correctly termed "imitation opal", as they contain substances not found in natural opal (such as plastic stabilizers). The imitation opals seen in vintage jewelry are often foiled glass, glass-based "Slocum stone", or later plastic materials.

Other research in macroporous structures have yielded highly ordered materials that have similar optical properties to opals and have been used in cosmetics.

Local atomic structure of opals

The lattice of spheres of opal that cause the interference with light are several hundred times larger than the fundamental structure of crystalline silica. As a mineraloid, no unit cell describes the structure of opal. Nevertheless, opals can be roughly divided into those that show no signs of crystalline order (amorphous opal) and those that show signs of the beginning of crystalline order, commonly termed cryptocrystalline or microcrystalline opal. Dehydration experiments and infrared spectroscopy have shown that most of the H₂O in the formula of SiO₂·nH₂O of opals is present in the familiar form of clusters of molecular water. Isolated water molecules, and silanols, structures such as SiOH, generally form a lesser proportion of the total and can reside near the surface or in defects inside the opal.

The structure of low-pressure polymorphs of anhydrous silica consist of frameworks of fully corner bonded tetrahedra of SiO₄. The higher temperature polymorphs of silica cristobalite and tridymite are frequently the first to crystallize from amorphous anhydrous silica, and the local structures of microcrystalline opals also appear to be closer to that of cristobalite and tridymite than to quartz. The structures of tridymite and cristobalite are closely related and can be described as hexagonal and cubic close-packed layers. It is therefore possible to have intermediate structures in which the layers are not regularly stacked.

Microcrystalline opal

Opal-CT has been interpreted as consisting of clusters of stacking of cristobalite and tridymite over very short length scales. The spheres of opal in opal-CT are themselves made up of tiny nanocrystalline blades of cristobalite and tridymite. Opal-CT has occasionally been further subdivided in the literature. Water content may be as high as 10 wt%. Lussatite is a synonym. Opal-C, also called lussatine, is interpreted as consisting of localized order of α-cristobalite with a lot of stacking disorder. Typical water content is about 1.5 wt%.

Noncrystalline opal

Two broad categories of noncrystalline opals, sometimes just referred to as "opal-A", have been proposed. The first of these is opal-AG consisting of aggregated spheres of silica, with water filling the space in between. Precious opal and potch opal are generally varieties of this, the difference being in the regularity of the sizes of the spheres and their packing. The second "opal-A" is opal-AN or water-containing amorphous silica-glass. Hyalite is another name for this.

Noncrystalline silica in siliceous sediments is reported to gradually transform to opal-CT and then opal-C as a result of diagenesis, due to the increasing overburden pressure in sedimentary rocks, as some of the stacking disorder is removed.

Etymology

The word 'opal' is adapted from the Latin term opalus, but the origin of this word is a matter of debate. However, most modern references suggest it is adapted from the Sanskrit word úpala.

References to the gem are made by Pliny the Elder. It is suggested to have been adapted from Ops, the wife of Saturn and goddess of fertility. The portion of Saturnalia devoted to Ops was "Opalia", similar to opalus.

Another common claim that the term is adapted from the Ancient Greek word, opallios. This word has two meanings, one is related to "seeing" and forms the basis of the English words like "opaque"; the other is "other" as in "alias" and "alter". It is claimed that opalus combined these uses, meaning "to see a change in color". However, historians have noted the first appearances of opallios do not occur until after the Romans had taken over the Greek states in 180 BC, and they had previously used the term paederos.

However, the argument for the Sanskrit origin is strong. The term first appears in Roman references around 250 BC, at a time when the opal was valued above all other gems. The opals were supplied by traders from the Bosporus, who claimed the gems were being supplied from India. Before this the stone was referred to by a variety of names, but these fell from use after 250 BC.

Historical superstitions

In the Middle Ages, opal was considered a stone that could provide great luck because it was believed to possess all the virtues of each gemstone whose color was represented in the color spectrum of the opal. It was also said to confer the power of invisibility if wrapped in a fresh bay leaf and held in the hand. Following the publication of Sir Walter Scott's Anne of Geierstein in 1829, opal acquired a less auspicious reputation. In Scott's novel, the Baroness of Arnheim wears an opal talisman with supernatural powers. When a drop of holy water falls on the talisman, the opal turns into a colorless stone and the Baroness dies soon thereafter. Due to the popularity of Scott's novel, people began to associate opals with bad luck and death. Within a year of the publishing of Scott's novel in April 1829, the sale of opals in Europe dropped by 50%, and remained low for the next 20 years or so.

Even as recently as the beginning of the 20th century, it was believed that when a Russian saw an opal among other goods offered for sale, he or she should not buy anything more, as the opal was believed to embody the evil eye.

Opal is considered the birthstone for people born in October.

Famous opals