Puneet Varma (Editor)

Meisserite

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Category
  
Sulfate mineral

Space group
  
P1

Crystal system
  
Triclinic

Formula (repeating unit)
  
Na5(UO2)(SO4)3(SO3OH)(H2O)

Crystal class
  
Pinacoidal (1) (same H-M symbol)

Unit cell
  
a = 5.32, b = 11.51, c = 13.56 [Å], α = 102.96°, β = 97.41°, γ = 91.46° (approximated); Z = 2

Meisserite is a very rare uranium mineral with the formula Na5(UO2)(SO4)3(SO3OH)(H2O). It is interesting in being a natural uranyl salt with hydrosulfate (hydroxysulfate) anion, a feature shared with belakovskiite. Other chemically related minerals include fermiite, oppenheimerite, natrozippeite and plášilite. Most of these uranyl sulfate minerals was originally found in the Blue Lizard mine, San Juan County, Utah, USA.The mineral is named after Swiss mineralogist Nicolas Meisser.

Contents

Association and origin

Meisserite is associated with other sulfate minerals: belakovskiite, johannite, chalcanthite, copiapite, ferrinatrite, and gypsum.It is resulting from post-mining oxidation of the primary uranium mineral - uraninite.

Crystal structure

The crystal structure of meisserite is unique. The building elements include:

  • pentagonal bypiramids of uranyl groups
  • SO4 groups
  • These elements link to form chains. Sodium cations are bonded to oxygen atoms in chains, to hydrosulfate groups and water.

    References

    Meisserite Wikipedia