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Isobutyraldehyde

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Formula
  
C4H8O

Molar mass
  
72.11 g/mol

Melting point
  
-65 °C

Density
  
790 kg/m³

Boiling point
  
63 °C

Appearance
  
colourless liquid

Isobutyraldehyde Isobutyraldehyde Wikipedia

Related alkyl aldehydes
  
Lilial Hexyl cinnamaldehyde 2-Methylundecanal

Related compounds
  
Butyraldehyde Propionaldehyde

Isobutyraldehyde is the chemical compound with the formula (CH3)2CHCHO. It is an aldehyde, isomeric with n-butyraldehyde (butanal). Isobutyraldehyde is manufactured, often as a side-product, by the hydroformylation of propene. Its odour is described as that of wet cereal or straw. It undergoes the Cannizaro reaction even though it has alpha hydrogen atom.

Contents

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Synthesis

Isobutyraldehyde is produced industrially by the hydroformylation of propene. Several million tons are produced annually.

Strong mineral acids catalyse the rearrangement of methallyl alcohol to isobutraldehyde.

It can also be produced using engineered bacteria.

Reactions

Hydrogenation of the aldehyde gives isobutanol. Oxidation gives methacrolein or methacrylic acid. Condensation with formaldehyde gives hydroxypivaldehyde.

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References

Isobutyraldehyde Wikipedia