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Let g be a Lie algebra over a field K. Let further
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Reductive Lie algebras
If g is reductive then the index of g is also the rank of g, because the adjoint and coadjoint representation are isomorphic and rk g is the minimal dimension of a stabilizer of an element in g. This is actually the dimension of the stabilizer of any regular element in g.
Frobenius Lie algebra
If ind g=0, then g is called Frobenius Lie algebra. This is equivalent to the fact that the Kirillov form