Supriya Ghosh (Editor)

Hypobromous acid

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Formula
  
HBrO

Hypobromous acid wwwchemspidercomImagesHandlerashxid75379ampw2

Hypobromous acid meaning


Hypobromous acid is a very weak and unstable acid with chemical formula of HOBr. It is also called bromic(I) acid, bromanol or hydroxidobromine. It occurs only in solution and has chemical and physical properties that are very similar to those of other hypohalites. Its salts (hypobromites) are also unstable.

Contents

Synthesis and properties

Addition of bromine to water gives hypobromous acid and hydrobromic acid (HBr) via a disproportionation reaction.

Br2 + H2O HOBr + HBr

Hypobromous acid has a pKa of 8.65 and is therefore only partially dissociated in water at pH 7. Like the acid, hypobromite salts are unstable and undergo a slow disproportionation reaction to yield the respective bromate and bromide salts.

3BrO(aq) → 2Br(aq) + BrO
3
(aq)

Uses

HOBr is used as a bleach, an oxidizer, a deodorant, and a disinfectant, due to its ability to kill the cells of many pathogens. The compound is generated in warm-blooded vertebrate organisms especially by eosinophils, which produce it by the action of eosinophil peroxidase, an enzyme which preferentially uses bromide. Bromide is also used in hot tubs and spas as a germicidal agent, using the action of an oxidizing agent to generate hypobromite in a similar fashion to the peroxidase in eosinophils. It is especially effective when used in combination with its congener, hypochlorous acid.

References

Hypobromous acid Wikipedia