Suvarna Garge (Editor)

1,3 Propane sultone

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Formula
  
C3H6O3S

Boiling point
  
112 °C

Density
  
1.39 g/cm³

Melting point
  
31 °C

1,3-Propane sultone wwwsigmaaldrichcomcontentdamsigmaaldrichstr

Appearance
  
White crystalline solid; colorless liquid above 31 °C

1,3-Propane sultone is the organosulfur compound with the formula (CH2)3SO3. It is a cyclic sulfonate ester, a class of compounds called sultones. It is a readily melting colorless solid.

Contents

Synthesis

It may be prepared by the acid catalyzed reaction of allyl alcohol and sodium bisulfite.

Reactions

1,3-propane sultone is an activated ester and is susceptible to nucleophilic attack. It hydrolyzes to the hydroxysulfonic acid.

It has been used in the synthesis of specialist surfactants, such as CHAPS detergent.

Safety

Typical of activated esters, 1,3-propane sultone is an alkylating agent. 1,3-Propane sultone is toxic, carcinogenic, mutagenic, and teratogenic.

References

1,3-Propane sultone Wikipedia