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Zinc–zinc oxide cycle

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Zinc–zinc oxide cycle

The zinc–zinc oxide cycle or Zn–ZnO cycle is a two step thermochemical cycle based on zinc and zinc oxide for hydrogen production with a typical efficiency around 40%.

Process description

The thermochemical two-step water splitting process uses redox systems:

  • Dissociation: ZnO → Zn + 1/2 O2
  • Hydrolysis: Zn + H2O → ZnO + H2
  • For the first endothermic step concentrating solar power is used in which zinc oxide is thermally dissociated at 1,900 °C (3,450 °F) into zinc and oxygen. In the second non-solar exothermic step zinc reacts at 427 °C (801 °F) with water and produces hydrogen and zinc oxide. The temperature level is realized by using a solar power tower and a set of heliostats to collect the solar thermal energy.

    References

    Zinc–zinc oxide cycle Wikipedia