Variable-range hopping, or Mott variable-range hopping, is a model describing low-temperature conduction in strongly disordered systems with localized charge-carrier states.
Contents
It has a characteristic temperature dependence of
for three-dimensional conductance, and in general for d-dimensions
Hopping conduction at low temperatures is of great interest because of the savings the semiconductor industry could achieve if they were able to replace single-crystal devices with glass layers.
Derivation
The original Mott paper introduced a simplifying assumption that the hopping energy depends inversely on the cube of the hopping distance (in the three-dimensional case). Later it was shown that this assumption was unnecessary, and this proof is followed here. In the original paper, the hopping probability at a given temperature was seen to depend on two parameters, R the spatial separation of the sites, and W, their energy separation. Apsley and Hughes noted that in a truly amorphous system, these variables are random and independent and so can be combined into a single parameter, the range
Mott showed that the probability of hopping between two states of spatial separation
where α−1 is the attenuation length for a hydrogen-like localised wave-function. This assumes that hopping to a state with a higher energy is the rate limiting process.
We now define
Conduction is the result of many series of hops through this four-dimensional array and as short-range hops are favoured, it is the average nearest-neighbour "distance" between states which determines the overall conductivity. Thus the conductivity has the form
where
The first step is to obtain
where
Then the probability that a state with range
the nearest-neighbour distribution.
For the d-dimensional case then
This can be evaluated by making a simple substitution of
After some algebra this gives
and hence that
Non-constant density of states
When the density of states is not constant (odd power law N(E)), the Mott conductivity is also recovered, as shown in this article.