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Tellimagrandin II

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Formula
  
C41H30O26

Pubchem
  
442679

Molar mass
  
938.66 g/mol

Tellimagrandin II httpsuploadwikimediaorgwikipediacommonsthu

Tellimagrandin II is the first of the ellagitannins formed from 1,2,3,4,6-pentagalloyl-glucose. It can be found in Geum japonicum and Syzygium aromaticum (clove).

Contents

Tellimagrandin II is an isomer of punicafolin or nupharin A, but the hexahydroxydiphenoyl group is not attached to the same hydroxyl groups in the glucose molecule.

The compound shows anti-herpesvirus properties.

Metabolism

It is formed by oxidation of pentagalloyl glucose in Tellima grandiflora by the enzyme pentagalloylglucose: O(2) oxidoreductase, a laccase-type phenol oxidase.

It is further oxidized to casuarictin, a molecule formed via oxidative dehydrogenation of 2 other galloyl groups in Casuarina and Stachyurus species.

Dimerization

It is laccase-catalyzed dimerized to cornusiin E in Tellima grandiflora.

References

Tellimagrandin II Wikipedia