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Strain crystallization

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Strain crystallization is a phenomenon in which an initially amorphous solid material undergoes a phase transformation due to the application of strain. Strain crystallization occurs in natural rubber and some other elastomers. The phenomenon has important effects on strength and fatigue properties. There are various techniques for measuring crystallization in rubber, including: x-ray diffraction, specific heat changes, and density changes. Crystallization can also be observed indirectly through its effects on stress–strain and fatigue behavior.

Contents

Elastomers that strain crystallize

  • Natural rubber (polyisoprene)
  • Polychloroprene
  • Elastomers that do not strain crystallize

  • Polybutadiene
  • Styrene-butadiene
  • References

    Strain crystallization Wikipedia