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In metallurgy, stainless steel, also known as inox steel or inox from French inoxydable (inoxidizable), is a steel alloy with a minimum of 10.5% chromium content by mass.
Contents
- Oxidation
- Acids
- Bases
- Organics
- Electricity and magnetism
- History
- Grades
- Standard finishes
- Architecture
- Locomotion
- Medicine
- Culinary use
- Jewelry
- Firearms
- 3D printing
- Maintenance
- Recycling and reusing
- Health effects
- References
Stainless steel is notable for its corrosion resistance, and it is widely used for food handling and cutlery among many other applications.
Stainless steel does not readily corrode, rust or stain with water as ordinary steel does. However, it is not fully stain-proof in low-oxygen, high-salinity, or poor air-circulation environments. There are various grades and surface finishes of stainless steel to suit the environment the alloy must endure. Stainless steel is used where both the properties of steel and corrosion resistance are required.
Stainless steel differs from carbon steel by the amount of chromium present. Unprotected carbon steel rusts readily when exposed to air and moisture. This iron oxide film (the rust) is active and accelerates corrosion by making it easier for more iron oxide to form. Since iron oxide has lower density than steel, the film expands and tends to flake and fall away. In comparison, stainless steels contain sufficient chromium to undergo passivation, forming an inert film of chromium oxide on the surface. This layer prevents further corrosion by blocking oxygen diffusion to the steel surface and stops corrosion from spreading into the bulk of the metal. Passivation occurs only if the proportion of chromium is high enough and oxygen is present.
Stainless steel’s resistance to corrosion and staining, low maintenance, and familiar lustre make it an ideal material for many applications. The alloy is milled into coils, sheets, plates, bars, wire, and tubing to be used in cookware, cutlery, household hardware, surgical instruments, major appliances, industrial equipment (for example, in sugar refineries) and as an automotive and aerospace structural alloy and construction material in large buildings. Storage tanks and tankers used to transport orange juice and other food are often made of stainless steel, because of its corrosion resistance. This also influences its use in commercial kitchens and food processing plants, as it can be steam-cleaned and sterilized and does not need paint or other surface finishes.
Oxidation
High oxidation resistance in air at ambient temperature is normally achieved with addition of a minimum of 13% (by weight) chromium, and up to 26% is used for harsh environments. The chromium forms a passivation layer of chromium(III) oxide (Cr2O3) when exposed to oxygen. The layer is too thin to be visible, and the metal remains lustrous and smooth. The layer is impervious to water and air, protecting the metal beneath, and this layer quickly reforms when the surface is scratched. This phenomenon is called passivation and is seen in other metals, such as aluminium and titanium. Corrosion resistance can be adversely affected if the component is used in a non-oxygenated environment, a typical example being underwater keel bolts buried in timber.
When stainless steel parts such as nuts and bolts are forced together, the oxide layer can be scraped off, allowing the parts to weld together. When forcibly disassembled, the welded material may be torn and pitted, a destructive effect known as galling. Galling can be avoided by the use of dissimilar materials for the parts forced together, for example bronze and stainless steel, or even different types of stainless steels (martensitic against austenitic). However, two different alloys electrically connected in a humid, even mildly acidic environment may act as a voltaic pile and corrode faster. Nitronic alloys, made by selective alloying with manganese and nitrogen, may have a reduced tendency to gall. Additionally, threaded joints may be lubricated to provide a film between the two parts and prevent galling. Low-temperature carburizing is another option that virtually eliminates galling and allows the use of similar materials without the risk of corrosion and the need for lubrication.
Acids
Stainless steel is generally highly resistant to attack from acids, but this quality depends on the kind and concentration of the acid, the surrounding temperature, and the type of steel. Type 904 is resistant to sulfuric acid at room temperature, even in high concentrations; types 316 and 317 are resistant below 10%; and type 304 should not be used in the presence of sulfuric acid at any concentration. All types of stainless steel resist attack from phosphoric acid, types 316 and 317 more so than 304; types 304L and 430 have been successfully used with nitric acid. Hydrochloric acid will damage any kind of stainless steel, and should be avoided.
Bases
The 300 series of stainless steel grades is unaffected by any of the weak bases such as ammonium hydroxide, even in high concentrations and at high temperatures. The same grades of stainless exposed to stronger bases such as sodium hydroxide at high concentrations and high temperatures will likely experience some etching and cracking, especially with solutions containing chlorides such as sodium hypochlorite.
Organics
Types 316 and 317 are both useful for storing and handling acetic acid, especially in solutions where it is combined with formic acid and when aeration is not present (oxygen helps protect stainless steel under such conditions), though 317 provides the greatest level of resistance to corrosion. Type 304 is also commonly used with formic acid though it will tend to discolor the solution. All grades resist damage from aldehydes and amines, though in the latter case grade 316 is preferable to 304; cellulose acetate will damage 304 unless the temperature is kept low. Fats and fatty acids only affect grade 304 at temperatures above 150 °C (302 °F), and grade 316 above 260 °C (500 °F), while 317 is unaffected at all temperatures. Type 316L is required for processing of urea.
Electricity and magnetism
Like steel, stainless steel is a relatively poor conductor of electricity, with significantly lower electrical conductivity than copper. Other metals in contact with stainless steel, particularly in a damp or acidic environment, may suffer galvanic corrosion even though the stainless metal may be unaffected.
Ferritic and martensitic stainless steels are magnetic. Annealed austenitic stainless steels are non-magnetic. Work hardening can make austenitic stainless steels slightly magnetic.
History
The corrosion resistance of iron-chromium alloys was first recognized in 1821 by French metallurgist Pierre Berthier, who noted their resistance against attack by some acids and suggested their use in cutlery. Metallurgists of the 19th century were unable to produce the combination of low carbon and high chromium found in most modern stainless steels, and the high-chromium alloys they could produce were too brittle to be practical.
In 1872, the Englishmen Clark and Woods patented an alloy that would today be considered a stainless steel.
In the late 1890s Hans Goldschmidt of Germany developed an aluminothermic (thermite) process for producing carbon-free chromium. Between 1904 and 1911 several researchers, particularly Leon Guillet of France, prepared alloys that would today be considered stainless steel.
Friedrich Krupp Germaniawerft built the 366-ton sailing yacht Germania featuring a chrome-nickel steel hull in Germany in 1908. In 1911, Philip Monnartz reported on the relationship between chromium content and corrosion resistance. On 17 October 1912, Krupp engineers Benno Strauss and Eduard Maurer patented austenitic stainless steel as Nirosta.
Similar developments were taking place contemporaneously in the United States, where Christian Dantsizen and Frederick Becket were industrializing ferritic stainless steel. In 1912, Elwood Haynes applied for a US patent on a martensitic stainless steel alloy, which was not granted until 1919.
In 1912, Harry Brearley of the Brown-Firth research laboratory in Sheffield, England, while seeking a corrosion-resistant alloy for gun barrels, discovered and subsequently industrialized a martensitic stainless steel alloy. The discovery was announced two years later in a January 1915 newspaper article in The New York Times. The metal was later marketed under the "Staybrite" brand by Firth Vickers in England and was used for the new entrance canopy for the Savoy Hotel in London in 1929. Brearley applied for a US patent during 1915 only to find that Haynes had already registered a patent. Brearley and Haynes pooled their funding and with a group of investors formed the American Stainless Steel Corporation, with headquarters in Pittsburgh, Pennsylvania.
In the beginning stainless steel was sold in the US under different brand names like "Allegheny metal" and "Nirosta steel". Even within the metallurgy industry the eventual name remained unsettled; in 1921 one trade journal was calling it "unstainable steel". In 1929, before the Great Depression hit, over 25,000 tons of stainless steel were manufactured and sold in the US.
There are different types of stainless steels: when nickel is added, for instance, the austenite structure of iron is stabilized. This crystal structure makes such steels virtually non-magnetic and less brittle at low temperatures. For greater hardness and strength, more carbon is added. With proper heat treatment, these steels are used for such products as razor blades, cutlery, and tools.
Significant quantities of manganese have been used in many stainless steel compositions. Manganese preserves an austenitic structure in the steel, similar to nickel, but at a lower cost.
Stainless steels are also classified by their crystalline structure:
Grades
There are over 150 grades of stainless steel, of which 15 are most commonly used. There are a number of systems for grading stainless and other steels, including US SAE steel grades.
Standard finishes
Standard mill finishes can be applied to flat rolled stainless steel directly by the rollers and by mechanical abrasives. Steel is first rolled to size and thickness and then annealed to change the properties of the final material. Any oxidation that forms on the surface (mill scale) is removed by pickling, and a passivation layer is created on the surface. A final finish can then be applied to achieve the desired aesthetic appearance.
Architecture
Stainless steel is used for buildings for both practical and aesthetic reasons. Stainless steel was in vogue during the art deco period. The most famous example of this is the upper portion of the Chrysler Building (pictured). Some diners and fast-food restaurants use large ornamental panels and stainless fixtures and furniture. Because of the durability of the material, many of these buildings still retain their original appearance. Stainless steel is used today in building construction because of its durability and because it is a weldable building metal that can be made into aesthetically pleasing shapes. An example of a building in which these properties are exploited is the Art Gallery of Alberta in Edmonton, which is wrapped in stainless steel.
Type 316 stainless is used on the exterior of both the Petronas Twin Towers and the Jin Mao Building, two of the world's tallest skyscrapers.
The Parliament House of Australia in Canberra has a stainless steel flagpole weighing over 220 tonnes (240 short tons).
The aeration building in the Edmonton Composting Facility, the size of 14 hockey rinks, is the largest stainless steel building in North America.
Stainless steel is a modern trend for roofing material for airports due to its low glare reflectance to keep pilots from being blinded, also for its properties that allow thermal reflectance in order to keep the surface of the roof close to ambient temperature. The Hamad International Airport in Qatar was built with all stainless steel roofing for these reasons, as well as the Sacramento International Airport in California.
Locomotion
The Allegheny Ludlum Corporation worked with Ford on various concept cars with stainless steel bodies from the 1930s through the 1970s to demonstrate the material's potential. The 1957 and 1958 Cadillac Eldorado Brougham had a stainless steel roof. In 1981 and 1982, the DeLorean DMC-12 production automobile used Type-304 stainless steel body panels over a glass-reinforced plastic monocoque. Intercity buses made by Motor Coach Industries are partially made of stainless steel. The aft body panel of the Porsche Cayman model (2-door coupe hatchback) is made of stainless steel. It was discovered during early body prototyping that conventional steel could not be formed without cracking (due to the many curves and angles in that automobile). Thus, Porsche was forced to use stainless steel on the Cayman.
Some automotive manufacturers use stainless steel as decorative highlights in their vehicles.
Rail cars have commonly been manufactured using corrugated stainless steel panels (for additional structural strength). This was particularly popular during the 1960s and 1970s, but has since declined. One notable example was the early Pioneer Zephyr. Notable former manufacturers of stainless steel rolling stock included the Budd Company (USA), which has been licensed to Japan's Tokyu Car Corporation, and the Portuguese company Sorefame. Many railcars in the United States are still manufactured with stainless steel, unlike other countries who have shifted away.
Budd also built two airplanes, the Budd BB-1 Pioneer and the Budd RB-1 Conestoga, of stainless steel tube and sheet. The first, which had fabric wing coverings, is on display at the Franklin Institute, being the longest continuous display of an aircraft ever, since 1934. The RB-2 Was almost all stainless steel, save for the control surfaces. One survives at the Pima Air & Space Museum, adjacent to Davis–Monthan Air Force Base.
The American Fleetwings Sea Bird amphibious aircraft of 1936 was also built using a spot-welded stainless steel hull.
Due to its thermal stability, the Bristol Aeroplane Company built the all-stainless steel Bristol 188 high-speed research aircraft, which first flew in 1963. However, the practical problems encountered meant that Concorde employed aluminium alloys.
The use of stainless steel in mainstream aircraft is hindered by its excessive weight compared to other materials, such as aluminium.
Medicine
Surgical tools and medical equipment are usually made of stainless steel, because of its durability and ability to be sterilized in an autoclave. In addition, surgical implants such as bone reinforcements and replacements (e.g. hip sockets and cranial plates) are made with special alloys formulated to resist corrosion, mechanical wear, and biological reactions in vivo.
Stainless steel is used in a variety of applications in dentistry. It is common to use stainless steel in many instruments that need to be sterilized, such as needles, endodontic files in root canal therapy, metal posts in root canal–treated teeth, temporary crowns and crowns for deciduous teeth, and arch wires and brackets in orthodontics. The surgical stainless steel alloys (e.g., 316 low-carbon steel) have also been used in some of the early dental implants.
Culinary use
Stainless steel is often preferred for kitchen sinks because of its ruggedness, durability, heat resistance, and ease of cleaning. In better models, acoustic noise is controlled by applying resilient undercoating to dampen vibrations. The material is also used for cladding of surfaces such as appliances and backsplashes.
Cookware and bakeware may be clad in stainless steels, to enhance their cleanability and durability, and to permit their use in induction cooking. Because stainless steel is a poor conductor of heat, it is often used as a thin surface cladding over a core of copper or aluminum, which conduct heat more readily.
Cutlery is normally stainless steel, both for low corrosion, ease of cleaning, negligible toxicity, as well as not flavoring the food by electrolytic activity.
Jewelry
Stainless steel is used for jewelry and watches, with 316L being the type commonly used for such applications. It can be re-finished by any jeweler and will not oxidize or turn black.
Valadium, a stainless steel and 12% nickel alloy is used to make class and military rings. Valadium is usually silver-toned, but can be electro-plated to give it a gold tone. The gold tone variety is known as Sun-lite Valadium. Other "Valadium" types of alloy are trade-named differently, with such names as "Siladium" and "White Lazon".
Firearms
Some firearms incorporate stainless steel components as an alternative to blued or parkerized steel. Some handgun models, such as the Smith & Wesson Model 60 and the Colt M1911 pistol, can be made entirely from stainless steel. This gives a high-luster finish similar in appearance to nickel plating. Unlike plating, the finish is not subject to flaking, peeling, wear-off from rubbing (as when repeatedly removed from a holster), or rust when scratched.
3D printing
Some 3D printing providers have developed proprietary stainless steel sintering blends for use in rapid prototyping. One of the more popular stainless steel grades used in 3D printing is 316L stainless steel. Due to the high temperature gradient and fast rate of solidification, stainless steel products manufactured via 3D printing tend to have a more refined microstructure; this in turn results in better mechanical properties. However, stainless steel is not used as much as materials like Ti6Al4V in the 3D printing industry; this is because manufacturing stainless steel products via traditional methods is currently much more economically competitive.
Maintenance
If treated or stored incorrectly, any grade of stainless steel may discolor or stain. To maintain optimum appearance, the surface should be cared for regularly.
The quality of installation affects the durability and lifespan of stainless steel. Therefore, it is important to make sure stainless steel is in good condition before installation. Normally, giving it a quick clean is enough prior to installation. However, if surface contamination is present, more attention is required. In fields such as aerospace, pharmaceuticals and food handling, an extremely high standard of cleanliness may be required, so extra care should be taken.
Maintenance is required to maintain the quality and appearance of steel. Depending on the environment, it is carried out between one and ten times per year. A proper maintenance routine significantly prolongs the life of stainless steel.
Abrasive cleaning tools should be avoided to prevent alteration of stainless steel finishes. Chloride-containing solutions, such as bleach, should also be avoided.
Despite its design and use, stainless steel can still be susceptible to corrosion, some grades more than others, and especially in corrosive environments. Challenging environments include saline environments, such as coastal areas where regular exposure to sea salt is common and areas where de-icing salts are common during winter. Manufacturing environments, especially in chemical and food industries, may also be subject to corrosive substances.
Stainless steel may also corrode if surfaces come into direct contact with iron or carbon steel. Trace particles from iron or carbon steel will rust on stainless steel surfaces. If left unattended, rust spots may compromise surface passivation and may spread internally. Contamination is common when stainless steel is subject to sparks from nearby welding, cutting, drilling, or grinding of carbon steel.
Corrosion can be treated by:
Recycling and reusing
Stainless steel is 100% recyclable. An average stainless steel object is composed of about 60% recycled material of which approximately 40% originates from end-of-life products and about 60% comes from manufacturing processes. According to the International Resource Panel's Metal Stocks in Society report, the per capita stock of stainless steel in use in society is 80–180 kg in more developed countries and 15 kg in less-developed countries.
There is a secondary market that recycles usable scrap for many stainless steel markets. The product is mostly coil, sheet, and blanks. This material is purchased at a less-than-prime price and sold to commercial quality stampers and sheet metal houses. The material may have scratches, pits, and dents but is made to the current specifications.
Health effects
Stainless steel is generally considered to be biologically inert, but some sensitive individuals develop a skin irritation due to a nickel allergy caused by certain alloys.