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Radium dials are watch, clock and other instrument dials painted with radioluminescent paint containing radium-226. The 1900s (decade) were the peak of radium dial production, as radiation poisoning was then unknown; subsequently, radium dials have largely been replaced by phosphorescent- or occasionally tritium-based light sources.
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Brands
History
Radium dials were almost always painted by young women, who used to 'point' their brushes by licking and shaping the bristles prior to painting the fine lines and numbers on the dials. This practice resulted in the ingestion of radium, which caused serious jaw-bone degeneration and malignancy and other dental diseases reminiscent of phossy jaw. The disease, radium-induced osteonecrosis, was recognized as an occupational disease in 1925 after a group of radium painters, known as the Radium Girls, from the United States Radium Corporation sued. By 1930, all dial painters stopped pointing their brushes by mouth. Stopping this practice drastically reduced the amount of radium ingested and therefore, the incidence of malignancy, to zero by 1950 among the workers who were studied.
"Luminous Processes employees interviewed by a journalist in 1978 had been left ignorant of radium's dangers. They were told that eliminating lippointing had ended earlier problems. They worked in unvented rooms, they wore smocks that they laundered at home. Geiger counters could pick up readings from pants returned from a dry cleaner and from clothes stored away in a cedar chest."
Safety
Although old radium dials may no longer produce light, this is frequently due to the breakdown of the crystal structure of zinc sulfide rather than the radioactive decay of the radium, which has a half-life of about 1600 years, so even very old radium dials remain radioactive. Radium paint can be ingested by inhaling flaking paint particles. The alpha particles emitted by the radium, which is taken up in bone, will kill off surrounding bone tissue, resulting in a condition loosely referred to as radium jaw. Inhaled or ingested particles may deposit a high local dose with a risk of lung or gastrointestinal cancer due to the radiation dose. The risks are hard to quantify due to the variable levels of radium in the paint and the quantity ingested or inhaled. Care should be taken in handling these materials especially where the paint is damaged.
The most common isotope of Radium is 226Ra, which primarily emits ionizing radiation: [alpha particles]. Alpha particles are shielded by most thin materials including paper. However, 226Ra only emits alpha particles 97 percent of the time with 186 keV gamma emission 3% of the time. Also, 226Ra is rarely present without other transuranic elements or decay products, which may emit beta or gamma radiation. Therefore, the radiation hazards from radium paint may not be entirely removed by the varnish, case or container. Care should be taken to prevent the inhalation or ingestion of flakes or dust which may contain radioactive materials. Radium dials have been shown to have dose rates near the face of in excess of 10uSv / hr, which would deliver a dose equivalent to one days background exposure in around 20 mins. This dose rate probably only represents the gamma emission as the alpha emission will be stopped by the lacquer or case. Hence the dose rate following ingestion or inhalation of the dust could be much higher.