Kalpana Kalpana (Editor)

Portlandite

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Category
  
Oxide mineral

Strunz classification
  
4.FE.05

Formula (repeating unit)
  
Ca(OH)2

Crystal system
  
Trigonal

Portlandite httpsuploadwikimediaorgwikipediacommonsthu

Dana classification
  
06.02.01.04 Brucite group

Crystal class
  
Hexagonal scalenohedral (3m) H-M symbol: (3 2/m)

Portlandite cif p1 cell mol2


Portlandite is a rare oxide mineral. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2).

Contents

Occurrence

Portlandite occurs in a variety of environments. At the type location in Northern Ireland it occurs as an alteration of calc–silicate rocks by contact metamorphism of larnite–spurrite. It occurs as fumarole deposits in the Vesuvius area. In Jebel Awq, Oman it occurs as precipitates from an alkaline spring emanating from ultramafic bedrock. In the Chelyabinsk coal basin of Russia it is produced by combustion of coal seams and similarly by spontaneous combustion of bitumen in the Hatrurim Formation of the Negev desert in Israel and the Maqarin area, Jordan. It also occurs in the manganese mining area of Kuruman, Cape Province, South Africa in the Kalahari Desert where it occurs as large crystals and masses.

It occurs in association with afwillite, calcite, larnite, spurrite, halite, brownmillerite, hydrocalumite, mayenite and ettringite.

It was first described in 1933 for an occurrence at Scawt Hill, Larne, County Antrim, Northern Ireland. It was named portlandite because the chemical calcium hydroxide is a common hydrolysis product of Portland cement.

References

Portlandite Wikipedia