Girish Mahajan (Editor)

Mercury selenide

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Formula
  
HgSe

Density
  
8.3 g/cm³

Molar mass
  
279.55 g/mol

Appearance
  
grey-black solid

Mercury selenide wwwemcoplateseagglojpg

Mse 220 14 mercury selenide phase


Mercury selenide (HgSe) is a chemical compound of mercury and selenium. It is a grey-black crystalline solid semi-metal with a sphalerite structure. The lattice constant is 0.608 nm.

Contents

Mercury selenide can also refer to the following chemical compounds: HgSe2 and HgSe8. HgSe is strictly mercury(II) selenide.

HgSe occurs naturally as the mineral Tiemannite.

Along with other II-VI compounds, colloidal nanocrystals of HgSe can be formed.

Applications

  • Selenium is used in filters in some steel plants to remove mercury from exhaust gases. The solid product formed is HgSe.
  • HgSe can be used as an ohmic contact to wide-gap II-VI semiconductors such as zinc selenide or zinc oxide.
  • Toxicity

    HgSe is non-toxic as long as it is not ingested due to its insolubility. Toxic hydrogen selenide fumes can be evolved on exposure to acids. HgSe is a relatively stable compound which might mean that it is less toxic than elemental mercury or many organometallic mercury compounds. Selenium's ability to complex with mercury has been proposed as a reason for the lack of mercury toxicity in deep sea fish despite high mercury levels.

    References

    Mercury selenide Wikipedia