listed alphabetically, after leader
Avengers #6-7, #9-10, #15-16 (vol. 1, Jul. 1964 - May 1965)
Baron Heinrich Zemo (leader)Black Knight (Nathan Garrett)EnchantressExecutionerMelterRadioactive ManWonder Man (sacrificed himself to save the Avengers)Avengers #54-55 (vol. 1, Jul. - Aug. 1968); #83 (vol. 1, Dec. 1970)
Ultron-5 (leader)Black Knight (Dane Whitman) (joined with the intention of betraying the Masters)KlawWhirlwindMelterRadioactive ManAvengers #222 (vol. 1, Aug. 1982); #227 - 229 (vol. 1, Jan. - Mar. 1983)
Egghead (leader)BeetleMoonstoneScorpion (Mac Gargan)Radioactive ManShocker (Herman Schultz)Tiger SharkWhirlwindAvengers #273 - 277 (vol. 1, Nov. 1986 - Mar. 1987)
Baron Helmut Zemo (leader)Absorbing ManBlackout (Marcus Daniels)Black Mamba (associate, appears as Tanya Sealy)Fixer (Paul Norbert Ebersol)Goliath (Erik Josten)Grey GargoyleMister HydeMoonstoneScreaming Mimi (new recruit)Tiger SharkTitaniaWhirlwindWrecking CrewBulldozerPiledriverThunderballWreckerYellowjacketDoctor Octopus (leader)Absorbing ManGargantuaJackhammerOddballPowderkegPuff AdderShocker (Herman Schultz)TitaniaYellowjacket (Rita DeMara)Avengers #270-277 (vol. 1, Aug. 1986 - Mar. 1987), Amazing Spider-Man #283 (vol. 1, Dec. 1986) and West Coast Avengers #16 (vol. 2, Jan. 1987).
Baron Helmut Zemo (leader)Beetle / MACH-1Fixer / TechnoGoliath / AtlasMoonstone / MeteoriteScreaming Mimi / SongbirdCrimson Cowl (leader)AqueductBisonBlackwingBoomerangCardinalConstrictorCyclone (Pierre Fresson)DragonflyEel (Edward Lavell)Flying TigerIcemasterJoystickKlawLodestoneMan-ApeMan-KillerQuicksandScorcherShatterfistShockwaveSlydeSunstrokeSuperchargerTiger SharkCrimson Cowl (leader)Black MambaCardinalCyclone (Pierre Fresson)Gypsy MothHydro-ManMachinesmithMan-KillerShadow Council's incarnation
Max Fury (first leader)Baron Helmut Zemo (second leader)Bi-BeastBlack Talon (Samuel Barone)Brothers Grimm (Percy and Barton Grimes)CarrionConstrictorCrossfireDaimon HellstromDiabloEelFirebrandGriffinKiller ShrikeLady Stilt-ManLasciviousLethaMadame MasqueMadcapPink PearlPorcupinePrincess PythonRingerSatannishSquid (Don Callahan)Tiger SharkTinkererVengeance (Kowalski)Whiplash (Anton Vanko)Wrecking CrewWreckerBulldozerPiledriverThunderballYoung MastersAlex WilderBlack KnightCoat of ArmsEggheadEnchantressExcavatorExecutionerMakoMelterMudbugRadioactive KidLightmaster (leader)Absorbing ManBlackoutMister HydeTitaniaWhirlwindWrecking CrewWreckerBulldozerPiledriverThunderballBaron Helmut Zemo (leader)KlawMan-KillerTiger SharkWhiplashWrecking CrewWreckerBulldozerPiledriverThunderballlisted alphabetically, after leader
AbominationBaron ZemoDoctor DoomLeaderUltronHood (Leader)Absorbing ManBatroc the LeaperBlizzard (Donnie Gill)Chemistro (Calvin Carr)Cobra (Klaus Voorhees)ConstrictorCrossbonesMadame MasqueMister HydeNitroSandmanTitaniaWizardThe Wrecking CrewBulldozerPiledriverThunderballWreckerDoctor Doom (Leader)ArcadeAttumaBaron MordoBullseyeByrrahCrimson Dynamo (Valentin Shatalov)DestroyerEnchantressExecutionerFin Fang FoomGrey GargoyleLizardLokiMandarinM.O.D.O.K.MysterioRadioactive ManRhinoScorpionShockerTiger SharkUltronWarlord KrangWinter SoldierThe Wrecking CrewBulldozerPiledriverThunderballWrecker