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Lignite, often referred to as brown coal, is a soft brown combustible sedimentary rock formed from naturally compressed peat. It is considered the lowest rank of coal due to its relatively low heat content. It has a carbon content around 60–70 percent. It is mined all around the world and is used almost exclusively as a fuel for steam-electric power generation, but is also mined for its germanium content in China.
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Characteristics
Lignite is brownish-black in color and has a carbon content around 60–70 percent, a high inherent moisture content sometimes as high as 75 percent, and an ash content ranging from 6–19 percent compared with 6–12 percent for bituminous coal.
The energy content of lignite ranges from 10 to 20 MJ/kg (9–17 million BTU per short ton) on a moist, mineral-matter-free basis. The energy content of lignite consumed in the United States averages 15 MJ/kg (13 million BTU/ton), on the as-received basis (i.e., containing both inherent moisture and mineral matter). The energy content of lignite consumed in Victoria, Australia, averages 8.4 MJ/kg (7.3 million BTU/ton).
Lignite has a high content of volatile matter which makes it easier to convert into gas and liquid petroleum products than higher-ranking coals. Unfortunately, its high moisture content and susceptibility to spontaneous combustion can cause problems in transportation and storage. It is now known that efficient processes which remove latent moisture locked within the structure of brown coal will relegate the risk of spontaneous combustion to the same level as black coal, transform the calorific value of brown coal to a black coal equivalent fuel, and significantly reduce the emissions profile of 'densified' brown coal to a level similar to or better than most black coals. However, removing the moisture increases the cost of the final lignite fuel.
Uses
Because of its low energy density and typically high moisture content, brown coal is inefficient to transport and is not traded extensively on the world market compared with higher coal grades. It is often burned in power stations near the mines, such as in Australia's Latrobe Valley and Luminant's Monticello plant in Texas. Primarily because of latent high moisture content and low energy density of brown coal, carbon dioxide emissions from traditional brown-coal-fired plants are generally much higher per megawatt generated than for comparable black-coal plants, with the world's highest-emitting plant being Hazelwood Power Station. The operation of traditional brown-coal plants, particularly in combination with strip mining, can be politically contentious due to environmental concerns.
As of 2014, about 12 percent of Germany's energy and, specifically, 27 percent of Germany's electricity comes from lignite power plants, while in Greece, lignite provides about 50 percent of its power needs.
An environmentally beneficial use of lignite can be found in its use in cultivation and distribution of biological control microbes that suppress plant disease causing microbes. The carbon enriches the organic matter in the soil while the biological control microbes provide an alternative to chemical pesticides
Reaction with quaternary amine forms a product called amine-treated lignite (ATL), which is used in drilling mud to reduce fluid loss during drilling.
Geology
Lignite begins as an accumulation of partially decayed plant material, or peat. Burial by other sediments results in increasing temperature, depending on the local geothermal gradient and tectonic setting, and increasing pressure. This causes compaction of the material and loss of some of the water and volatile matter (primarily methane and carbon dioxide). This process, called coalification, concentrates the carbon content, and thus the heat content, of the material. Deeper burial and the passage of time result in further expulsion of moisture and volatile matter, eventually transforming the material into higher rank coals such as bituminous and anthracite coal.
Lignite deposits are typically younger than higher-ranked coals, with the majority of them having formed during the Tertiary period.
Types
Lignite can be separated into two types. The first is xyloid lignite or fossil wood and the second form is the compact lignite or perfect lignite.
Although xyloid lignite may sometimes have the tenacity and the appearance of ordinary wood, it can be seen that the combustible woody tissue has experienced a great modification. It is reducible to a fine powder by trituration, and if submitted to the action of a weak solution of potash, it yields a considerable quantity of humic acid. Leonardite is an oxidized form of lignite, which is also contains high levels of humic acid.
Jet is a hardened, gem-like form of lignite used in various types of jewelry.