Rahul Sharma (Editor)

Iodine trichloride

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Formula
  
I2Cl6

Melting point
  
63 °C

Appearance
  
yellow solid

Molar mass
  
466.5281 g/mol

Density
  
3.11 g/cm³

Iodine trichloride FileIodinetrichloridedimer3Dballspng Wikimedia Commons

Vsepr theory iodine trichloride icl3 expanded valence


Iodine trichloride is an interhalogen compound of iodine and chlorine. It is bright yellow and in the solid state is present as a planar dimer I2Cl6, Cl2I(μ-Cl)2ICl2, with two bridging Cl atoms.

Contents

Iodine trichloride Iodine trichloride Wikipedia

It can be prepared by reacting iodine with an excess of liquid chlorine at −70 °C. In the melt it is conductive, which may indicate dissociation:

Iodine trichloride wwwchemspidercomImagesHandlerashxid63265ampw2
I2Cl6 ⇌ ICl2+ + ICl4

Iodine trichloride can be created by heating a mixture of liquid iodine and chlorine gas to 105 °C.

It is an oxidizing agent, capable of causing fire on contact with organic materials.

Vsepr theory iodine trichloride icl3 expanded valence


Iodine trichloride Iodine trichloride 97 SigmaAldrich

References

Iodine trichloride Wikipedia