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Griffiths inequality

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In statistical mechanics, the Griffiths inequality, sometimes also called Griffiths–Kelly–Sherman inequality or GKS inequality, named after Robert B. Griffiths, is a correlation inequality for ferromagnetic spin systems. Informally, it says that in ferromagnetic spin systems, if the 'a-priori distribution' of the spin is invariant under spin flipping, the correlation of any monomial of the spins is non-negative; and the two point correlation of two monomial of the spins is non-negative.

Contents

The inequality was proved by Griffiths for Ising ferromagnets with two-body interactions, then generalised by Kelly and Sherman to interactions involving an arbitrary number of spins, and then by Griffiths to systems with arbitrary spins. A more general formulation was given by Ginibre, and is now called the Ginibre inequality.

Definitions

Let σ = { σ j } j Λ be a configuration of (continuous or discrete) spins on a lattice Λ. If AΛ is a list of lattice sites, possibly with duplicates, let σ A = j A σ j be the product of the spins in A.

Assign an a-priori measure dμ(σ) on the spins; let H be an energy functional of the form

H ( σ ) = A J A σ A   ,

where the sum is over lists of sites A, and let

Z = d μ ( σ ) e H ( σ )

be the partition function. As usual,

= 1 Z σ ( σ ) e H ( σ )

stands for the ensemble average.

The system is called ferromagnetic if, for any list of sites A, JA ≥ 0. The system is called invariant under spin flipping if, for any j in Λ, the measure μ is preserved under the sign flipping map σ → τ, where

τ k = { σ k , k j , σ k , k = j .

First Griffiths inequality

In a ferromagnetic spin system which is invariant under spin flipping,

σ A 0

for any list of spins A.

Second Griffiths inequality

In a ferromagnetic spin system which is invariant under spin flipping,

σ A σ B σ A σ B

for any lists of spins A and B.

The first inequality is a special case of the second one, corresponding to B = ∅.

Proof

Observe that the partition function is non-negative by definition.

Proof of first inequality: Expand

e H ( σ ) = B k 0 J B k σ B k k ! = { k C } C B J B k B σ B k B k B !   ,

then

Z σ A = d μ ( σ ) σ A e H ( σ ) = { k C } C B J B k B k B ! d μ ( σ ) σ A σ B k B = { k C } C B J B k B k B ! d μ ( σ ) j Λ σ j n A ( j ) + n B ( j )   ,

where nA(j) stands for the number of times that j appears in A. Now, by invariance under spin flipping,

d μ ( σ ) j σ j n ( j ) = 0

if at least one n(j) is odd, and the same expression is obviously non-negative for even values of n. Therefore, Z<σA>≥0, hence also <σA>≥0.

Proof of second inequality. For the second Griffiths inequality, double the random variable, i.e. consider a second copy of the spin, σ , with the same distribution of σ . Then

σ A σ B σ A σ B = σ A ( σ B σ B )   .

Introduce the new variables

σ j = τ j + τ j   , σ j = τ j τ j   .

The doubled system is ferromagnetic in τ , τ because H ( σ ) H ( σ ) is a polynomial in τ , τ with positive coefficients

A J A ( σ A + σ A ) = A J A X A [ 1 + ( 1 ) | X | ] τ A X τ X

Besides the measure on τ , τ is invariant under spin flipping because d μ ( σ ) d μ ( σ ) is. Finally the monomials σ A , σ B σ B are polynomials in τ , τ with positive coefficients

σ A = X A τ A X τ X   , σ B σ B = X B [ 1 ( 1 ) | X | ] τ B X τ X   .

The first Griffiths inequality applied to σ A ( σ B σ B ) gives the result.

More details are in.

Extension: Ginibre inequality

The Ginibre inequality is an extension, found by Jean Ginibre, of the Griffiths inequality.

Formulation

Let (Γ, μ) be a probability space. For functions fh on Γ, denote

f h = f ( x ) e h ( x ) d μ ( x ) / e h ( x ) d μ ( x ) .

Let A be a set of real functions on Γ such that. for every f1,f2,...,fn in A, and for any choice of signs ±,

d μ ( x ) d μ ( y ) j = 1 n ( f j ( x ) ± f j ( y ) ) 0.

Then, for any f,g,−h in the convex cone generated by A,

f g h f h g h 0.

Proof

Let

Z h = e h ( x ) d μ ( x ) .

Then

Z h 2 ( f g h f h g h ) = d μ ( x ) d μ ( y ) f ( x ) ( g ( x ) g ( y ) ) e h ( x ) h ( y ) = k = 0 d μ ( x ) d μ ( y ) f ( x ) ( g ( x ) g ( y ) ) ( h ( x ) h ( y ) ) k k ! .

Now the inequality follows from the assumption and from the identity

f ( x ) = 1 2 ( f ( x ) + f ( y ) ) + 1 2 ( f ( x ) f ( y ) ) .

Examples

  • To recover the (second) Griffiths inequality, take Γ = {−1, +1}Λ, where Λ is a lattice, and let μ be a measure on Γ that is invariant under sign flipping. The cone A of polynomials with positive coefficients satisfies the assumptions of the Ginibre inequality.
  • (Γ, μ) is a commutative compact group with the Haar measure, A is the cone of real positive definite functions on Γ.
  • Γ is a totally ordered set, A is the cone of real positive non-decreasing functions on Γ. This yields Chebyshev's sum inequality. For extension to partially ordered sets, see FKG inequality.
  • Applications

  • The thermodynamic limit of the correlations of the ferromagnetic Ising model (with non-negative external field h and free boundary conditions) exists.
  • This is because increasing the volume is the same as switching on new couplings JB for a certain subset B. By the second Griffiths inequality J B σ A = σ A σ B σ A σ B 0 Hence σ A is monotonically increasing with the volume; then it converges since it is bounded by 1.
  • The one-dimensional, ferromagnetic Ising model with interactions J x , y | x y | α displays a phase transition if 1 < α < 2 .
  • This property can be shown in a hierarchical approximation, that differs from the full model by the absence of some interactions: arguing as above with the second Griffiths inequality, the results carries over the full model.
  • The Ginibre inequality provides the existence of the thermodynamic limit for the free energy and spin correlations for the two-dimensional classical XY model. Besides, through Ginibre inequality, Kunz and Pfister proved the presence of a phase transition for the ferromagnetic XY model with interaction J x , y | x y | α if 2 < α < 4 .
  • Aizenman and Simon used the Ginibre inequality to prove that the two point spin correlation of the ferromagnetic classical XY model in dimension D , coupling J > 0 and inverse temperature β is dominated by (i.e. has upper bound given by) the two point correlation of the ferromagnetic Ising model in dimension D , coupling J > 0 , and inverse temperature β / 2
  • Hence the critical β of the XY model cannot be smaller than the double of the critical temperature of the Ising model β c X Y 2 β c I s   ; in dimension D = 2 and coupling J = 1, this gives β c X Y ln ( 1 + 2 ) 0.88   .
  • There exists a version of the Ginibre inequality for the Coulomb gas that implies the existence of thermodynamic limit of correlations.
  • Other applications (phase transitions in spin systems, XY model, XYZ quantum chain) are reviewed in.
  • References

    Griffiths inequality Wikipedia