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Geminal diol

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Geminal diol chemistry world

Cyanohydrin and geminal diol formation

A geminal diol (or gem-diol for short) is any organic compound having two hydroxyl functional groups (-OH) bound to the same carbon atom.


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The simplest geminal diol is methanediol CH4O2 or H2C(OH)2. Other examples are dihydroxymalonic acid HOOC-C(OH)2-COOH and decahydroxycyclopentane (C(OH)2)5.

Geminal diols are a subclass of the diols, which in turn are a special class of alcohols. Geminal diols can also be viewed as an analog of hemiacetals formed by reaction of carbonyl compounds with water, instead of with an alcohol.

Geminal diol Gem Diol OChemPal

The two hydroxyls in a geminal diol are easily converted to a carbonyl or keto group C=O by loss of one water molecule, thus turning the diol into a ketone. Conversely, ketones tend to combine with water to form the corresponding geminal diols. The equilibrium in water solution may be shifted towards either compound; for example, the equilibrium constant for the conversion of acetone (H3C)2C=O to propane-2,2-diol (H3C)2C(OH)2 is about 10−3, while that of formaldehyde H2C=O to methanediol H2C(OH)2 is 10+3, and that of hexafluoroacetone (F3C)2C=O to hexafluoropropane-2,2-diol (F3C)2C(OH)2 is about 10+6. In some cases, such as decahydroxycyclopentane and dodecahydroxycyclohexane, the geminal diol is stable while the ketone is not.

Geminal diol 128 Reactions of Aldehydes and Ketones with Water Chemistry

Geminal diol meaning

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