Density 1.95 g/cm³ Boiling point 72.2 °C | Formula C2H5I Appearance Colourless liquid | |
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Related iodoalkanes Related compounds | ||
Ethyl iodide (also iodoethane) is a colorless, flammable chemical compound. It has the chemical formula C2H5I and is prepared by heating ethanol with iodine and phosphorus. On contact with air, especially on the effect of light, it decomposes and turns yellow or reddish from dissolved iodine. It may also be prepared by reaction between hydroiodic acid and ethanol distilling off the ethyl iodide. Ethyl iodide should be stored in copper powder to avoid fast decomposition, though even with this method samples don't last more than 1 year.
Because iodide is a good leaving group, ethyl iodide is an excellent ethylating agent. It is also used as the hydrogen radical promoter.
Production
Ethyl iodide is prepared by using red phosphorus, absolute ethanol and iodine ; the phosphorus and iodine dissolve in the ethanol, where they form phosphorus triiodide, which must be formed in situ because it is unstable. During the process the temperature is controlled.
The crude product is purified by distillation.
