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Ethenium

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Ethenium

In chemistry, ethenium or protonated ethylene is a positive ion with the formula C
2
H+
5
. It can be viewed as a molecule of ethylene (C
2
H
4
) with one added proton (H+
), or a molecule of ethane (C
2
H
6
) minus one hydride ion (H
). It is a carbocation; more specifically, a carbonium ion.

Contents

Preparation

Ethenium has been observed in rarefied gases subjected to radiation. Another preparation method is to react certain proton donors such as H+
3
, HeH+
, N
2
H+
, and N
2
OH+
with ethane at ambient temperature and pressures below 1 mmHg. (Other donors such as CH+
5
and HCO+
form ethanium preferably to ethenium.)

At room temperature and in a rarefied methane atmosphere, ethanium slowly dissociates to ethenium and H
2
. The reaction is much faster at 90 °C.

Stability and reactions

Contrary to some earlier reports, ethenium was found to be largely unreactive towards neutral methane at ambient temperature and low pressure (on the order of 1 mmHg), even though the reaction yielding sec-C
3
H+
7
and H
2
is believed to be exothermic.

Structure

The structure of ethenium's ground state was in dispute for many years, but it was eventually agreed to be a non-classical structure, with the two carbon atoms and one of the hydrogen atoms forming a three-center two-electron bond.

References

Ethenium Wikipedia


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