Formula C8H18O | Appearance Colorless liquid | |
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Dibutyl ether is a chemical compound belonging to the ether family with the molecular formula of C
8H
18O. It is colorless, volatile, and flammable liquid and has peculiar ethereal smell.
Contents
Liquid dibutyl ether is lighter than water. On the other hand, the vapor is heavier than air. It is not soluble in water, but it is soluble in acetone and many other organic solvents. Due to this property, dibutyl ether is used as solvent in various chemical reactions and processes. For example, phenyllithium is commercially available as a ca. 1.8 M solution in dibutyl ether.
Because of the formation of peroxides, it should be protected from heat, light and air.
Synthesis
Dibutyl ether is obtained from dehydration of 1-butanol with sulfuric acid as a catalyst and dehydrating agent:
2C4H
9OH → C
8H
18O + H
2O
Industrially, dibutyl ether can be obtained by dehydration of 1-butanol on alumina at 300 °C.
Reactions
This compound is generally stable to oxidation, reduction, and base. Strong acids like HI and HBr can cleave this ether. In the presence of oxygen, dibutyl ether is oxidized to a peroxide or hydroperoxide.
Applications
