Girish Mahajan (Editor)

Cylindrical multipole moments

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Cylindrical multipole moments

Cylindrical multipole moments are the coefficients in a series expansion of a potential that varies logarithmically with the distance to a source, i.e., as ln   R . Such potentials arise in the electric potential of long line charges, and the analogous sources for the magnetic potential and gravitational potential.

Contents

For clarity, we illustrate the expansion for a single line charge, then generalize to an arbitrary distribution of line charges. Through this article, the primed coordinates such as ( ρ , θ ) refer to the position of the line charge(s), whereas the unprimed coordinates such as ( ρ , θ ) refer to the point at which the potential is being observed. We use cylindrical coordinates throughout, e.g., an arbitrary vector r has coordinates ( ρ , θ , z ) where ρ is the radius from the z axis, θ is the azimuthal angle and z is the normal Cartesian coordinate. By assumption, the line charges are infinitely long and aligned with the z axis.

Cylindrical multipole moments of a line charge

The electric potential of a line charge λ located at ( ρ , θ ) is given by

Φ ( ρ , θ ) = λ 2 π ϵ ln R = λ 4 π ϵ ln | ρ 2 + ( ρ ) 2 2 ρ ρ cos ( θ θ ) |

where R is the shortest distance between the line charge and the observation point.

By symmetry, the electric potential of an infinite linecharge has no z -dependence. The line charge λ is the charge per unit length in the z -direction, and has units of (charge/length). If the radius ρ of the observation point is greater than the radius ρ of the line charge, we may factor out ρ 2

Φ ( ρ , θ ) = λ 4 π ϵ { 2 ln ρ + ln ( 1 ρ ρ e i ( θ θ ) ) ( 1 ρ ρ e i ( θ θ ) ) }

and expand the logarithms in powers of ( ρ / ρ ) < 1

Φ ( ρ , θ ) = λ 2 π ϵ { ln ρ k = 1 ( 1 k ) ( ρ ρ ) k [ cos k θ cos k θ + sin k θ sin k θ ] }

which may be written as

Φ ( ρ , θ ) = Q 2 π ϵ ln ρ + ( 1 2 π ϵ ) k = 1 C k cos k θ + S k sin k θ ρ k

where the multipole moments are defined as
Q = λ ,
C k = λ k ( ρ ) k cos k θ ,
and
S k = λ k ( ρ ) k sin k θ .

Conversely, if the radius ρ of the observation point is less than the radius ρ of the line charge, we may factor out ( ρ ) 2 and expand the logarithms in powers of ( ρ / ρ ) < 1

Φ ( ρ , θ ) = λ 2 π ϵ { ln ρ k = 1 ( 1 k ) ( ρ ρ ) k [ cos k θ cos k θ + sin k θ sin k θ ] }

which may be written as

Φ ( ρ , θ ) = Q 2 π ϵ ln ρ + ( 1 2 π ϵ ) k = 1 ρ k [ I k cos k θ + J k sin k θ ]

where the interior multipole moments are defined as
Q = λ ,
I k = λ k cos k θ ( ρ ) k ,
and
J k = λ k sin k θ ( ρ ) k .

General cylindrical multipole moments

The generalization to an arbitrary distribution of line charges λ ( ρ , θ ) is straightforward. The functional form is the same

Φ ( r ) = Q 2 π ϵ ln ρ + ( 1 2 π ϵ ) k = 1 C k cos k θ + S k sin k θ ρ k

and the moments can be written

Q = d θ ρ d ρ λ ( ρ , θ ) C k = ( 1 k ) d θ d ρ ( ρ ) k + 1 λ ( ρ , θ ) cos k θ S k = ( 1 k ) d θ d ρ ( ρ ) k + 1 λ ( ρ , θ ) sin k θ

Note that the λ ( ρ , θ ) represents the line charge per unit area in the ( ρ θ ) plane.

Interior cylindrical multipole moments

Similarly, the interior cylindrical multipole expansion has the functional form

Φ ( ρ , θ ) = Q 2 π ϵ ln ρ + ( 1 2 π ϵ ) k = 1 ρ k [ I k cos k θ + J k sin k θ ]

where the moments are defined

Q = d θ ρ d ρ λ ( ρ , θ ) I k = ( 1 k ) d θ d ρ [ cos k θ ( ρ ) k 1 ] λ ( ρ , θ ) J k = ( 1 k ) d θ d ρ [ sin k θ ( ρ ) k 1 ] λ ( ρ , θ )

Interaction energies of cylindrical multipoles

A simple formula for the interaction energy of cylindrical multipoles (charge density 1) with a second charge density can be derived. Let f ( r ) be the second charge density, and define λ ( ρ , θ ) as its integral over z

λ ( ρ , θ ) = d z   f ( ρ , θ , z )

The electrostatic energy is given by the integral of the charge multiplied by the potential due to the cylindrical multipoles

U = d θ ρ d ρ   λ ( ρ , θ ) Φ ( ρ , θ )

If the cylindrical multipoles are exterior, this equation becomes

U = Q 1 2 π ϵ ρ d ρ   λ ( ρ , θ ) ln ρ                     +   ( 1 2 π ϵ ) k = 1 C 1 k d θ d ρ [ cos k θ ρ k 1 ] λ ( ρ , θ )                 +   ( 1 2 π ϵ ) k = 1 S 1 k d θ d ρ [ sin k θ ρ k 1 ] λ ( ρ , θ )

where Q 1 , C 1 k and S 1 k are the cylindrical multipole moments of charge distribution 1. This energy formula can be reduced to a remarkably simple form

U = Q 1 2 π ϵ ρ d ρ   λ ( ρ , θ ) ln ρ + ( 1 2 π ϵ ) k = 1 k ( C 1 k I 2 k + S 1 k J 2 k )

where I 2 k and J 2 k are the interior cylindrical multipoles of the second charge density.

The analogous formula holds if charge density 1 is composed of interior cylindrical multipoles

U = Q 1 ln ρ 2 π ϵ ρ d ρ   λ ( ρ , θ ) + ( 1 2 π ϵ ) k = 1 k ( C 2 k I 1 k + S 2 k J 1 k )

where I 1 k and J 1 k are the interior cylindrical multipole moments of charge distribution 1, and C 2 k and S 2 k are the exterior cylindrical multipoles of the second charge density.

As an example, these formulae could be used to determine the interaction energy of a small protein in the electrostatic field of a double-stranded DNA molecule; the latter is relatively straight and bears a constant linear charge density due to the phosphate groups of its backbone.

References

Cylindrical multipole moments Wikipedia