Harman Patil (Editor)

Chlorine pentafluoride

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Formula
  
ClF5

Melting point
  
-103 °C

Boiling point
  
-13.1 °C

Molar mass
  
130.445 g/mol

Density
  
4.5 g/cm³

Appearance
  
colorless gas

Chlorine pentafluoride httpsiytimgcomviLHW6rOJv9Imaxresdefaultjpg

Chlorine pentafluoride clf5 lewis dot structure


Chlorine pentafluoride is an interhalogen compound with formula ClF5. This colourless gas is a strong oxidant that was once a candidate oxidizer for rockets. The molecule adopts a square pyramidal structure with C4v symmetry, as confirmed by its high resolution 19F NMR spectrum.

Contents

Clf5 lewis structure how to draw the lewis structure for clf5 chlorine pentafluoride


Preparation

Some of the earliest research on the preparation was classified. It was first prepared by fluorination of chlorine trifluoride at high temperatures and high pressures:

ClF3 + F2 → ClF5

NiF2 catalyzes this reaction.

Certain metal fluorides, MClF4 (i.e. KClF4, RbClF4, CsClF4) react with F2 to produce ClF5 and the corresponding alkali metal fluoride.

Reactions

In a highly exothermic reaction, water hydrolyses ClF5 to produce chloryl fluoride and hydrogen fluoride:

ClF
5
+ 2 H
2
O
FClO
2
+ 4 HF

It is also a strong fluorinating agent. At room temperature it reacts readily with all elements except noble gases, nitrogen, oxygen and fluorine.

References

Chlorine pentafluoride Wikipedia


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