Neha Patil (Editor)

Cadmium cyanide

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Formula
  
Cd(CN)2

Density
  
2.23 g/cm³

Molar mass
  
164.45 g/mol

Appearance
  
white cubic crystals

Cadmium cyanide is an inorganic compound with the formula Cd(CN)2. This white crystalline compound is used in electroplating. It is very toxic, along with other cadmium and cyanide compounds.

Contents

Usage

It is used as an electrolyte for electrodeposition of thin metallic cadmium coatings on metal to protect against corrosion.

Preparation and structure

Cadmium cyanide is prepared by treating cadmium hydroxide with hydrogen cyanide:

Cd(OH)2 + 2 HCN → Cd(CN)2 + 2 H2O

It adopts a diamondoid structure, like Zn(CN)2.

Reactions

Like zinc cyanide, cadmium cyanide is fairly soluble in water, which is unusual for metal cyanides. The solubility increases with the additional cyanide, this reaction proceeding via "[Cd(CN)3]" and [Cd(CN)4]2−. With acids, its solutions evolve hydrogen cyanide.

References

Cadmium cyanide Wikipedia