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In quantum mechanics, bra–ket notation is a standard notation for describing quantum states. The notation uses angle brackets ("
Contents
- Usage
- Background Vector spaces
- Ket notation for vectors
- Inner products and bras
- Bras and kets as row and column vectors
- Bras as linear transformation on kets
- Non normalizable states and non Hilbert spaces
- Usage in quantum mechanics
- Spinless positionspace wave function
- Overlap of states
- Changing basis for a spin 12 particle
- Misleading uses
- Linear operators acting on kets
- Linear operators acting on bras
- Outer products
- Hermitian conjugate operator
- Properties
- Linearity
- Associativity
- Hermitian conjugation
- Composite bras and kets
- The unit operator
- Notation used by mathematicians
- References
consisting of a left part,
called the bra /brɑː/, and a right part,
called the ket /kɛt/. The notation was introduced in 1939 by Paul Dirac and is also known as the Dirac notation, though the notation has precursors in Hermann Grassmann's use of the notation
for his inner products nearly 100 years earlier. The relevant quantity is actually
and is interpreted according to the fundamental Born rule.
Usage
Bra–ket notation is widespread in quantum mechanics. Many phenomena that are explained using quantum mechanics are usually most clearly demonstrated with the help of the bra-ket notation. Part of the appeal of the notation is the abstract representation-independence it encodes, together with its versatility in producing a specific representation (e.g. x, or p, or eigenfunction base) without much ado, or excessive reliance on the nature of the linear spaces involved.
The standard mathematical notation for the inner product, preferred as well by some physicists, expresses exactly the same thing as the bra-ket notation,
where the far right gives the value of the linear functional (the bra) on its argument (the ket), and one can choose freely to interpret the left argument of ⟨·|⋅⟩ as either a bra or a ket according to whether the far right or far left expression is the one thought of. It is only when a bra appears unpaired in an expression, such as,
that one should be aware that the bra technically is an element of the dual space of Hilbert space. It is in handling expressions containing these that the Dirac notation comes into its own. The notation does not introduce or imply any new physics.
Background: Vector spaces
In physics, basis vectors allow any Euclidean vector to be represented geometrically using angles and lengths, in different directions, i.e. in terms of the spatial orientations. It is simpler to see the notational equivalences between ordinary notation and bra-ket notation; so, for now, consider a vector A starting at the origin and ending at an element of 3-d Euclidean space; the vector then is specified by this end-point, a triplet of elements in the field of real numbers, symbolically dubbed as A ∈ ℝ3.
The vector A can be written using any set of basis vectors and corresponding coordinate system. Informally, basis vectors are like "building blocks of a vector": they are added together to compose a vector, and the coordinates are the numerical coefficients of basis vectors in each direction. Two useful representations of a vector are simply a linear combination of basis vectors, and column matrices. Using the familiar Cartesian basis, a vector A may be written as
respectively, where ex, ey, ez denote the Cartesian basis vectors (all are orthogonal unit vectors) and Ax, Ay, Az are the corresponding coordinates, in the x, y, z directions. In a more general notation, for any basis in 3-d space one writes
Generalizing further, consider a vector A in an N-dimensional vector space over the field of complex numbers ℂ, symbolically stated as A ∈ ℂN. The vector A is still conventionally represented by a linear combination of basis vectors or a column matrix:
though the coordinates are now all complex-valued.
Even more generally, A can be a vector in a complex Hilbert space. Some Hilbert spaces, like ℂN, have finite dimension, while others have infinite dimension. In an infinite-dimensional space, the column-vector representation of A would be a list of infinitely many complex numbers.
Ket notation for vectors
Rather than such conventions as bold type, over arrows, and underscores (i.e.,
or in a more easily generalized notation,
The last one may be written in short as
Note how any symbols, letters, numbers, or even words—whatever serves as a convenient label—can be used as the label inside a ket. In other words, the symbol "
Inner products and bras
An inner product is a generalization of the dot product. The inner product of two vectors is a scalar. Bra-ket notation uses a specific notation for inner products:
For example, in three-dimensional complex Euclidean space,
where
Bra–ket notation splits this inner product (also called a "bracket") into two pieces, the "bra" and the "ket":
where
The purpose of "splitting" the inner product into a bra and a ket is that both the bra
Bras and kets as row and column vectors
For a finite-dimensional vector space, using a fixed orthonormal basis, the inner product can be written as a matrix multiplication of a row vector with a column vector:
Based on this, the bras and kets can be defined as:
and then it is understood that a bra next to a ket implies matrix multiplication.
The conjugate transpose (also called Hermitian conjugate) of a bra is the corresponding ket and vice versa:
because if one starts with the bra
then performs a complex conjugation, and then a matrix transpose, one ends up with the ket
Bras as linear transformation on kets
A more abstract definition, which is equivalent but more easily generalized to infinite-dimensional spaces, is to say that bras are linear functionals on kets, i.e. linear transformations that input a ket and output a complex number. The bra linear functionals are defined to be consistent with the inner product.
In mathematics terminology, the vector space of bras is the dual space to the vector space of kets, and corresponding bras and kets are related by the Riesz representation theorem.
Non-normalizable states and non-Hilbert spaces
Bra-ket notation can be used even if the vector space is not a Hilbert space.
In quantum mechanics, it is common practice to write down kets which have infinite norm, i.e. non-normalizable wavefunctions. Examples include states whose wavefunctions are Dirac delta functions or infinite plane waves. These do not, technically, belong to the Hilbert space itself. However, the definition of "Hilbert space" can be broadened to accommodate these states (see the Gelfand–Naimark–Segal construction or rigged Hilbert spaces). The bra-ket notation continues to work in an analogous way in this broader context.
For a rigorous treatment of the Dirac inner product of non-normalizable states, see the definition given by D. Carfì. For a rigorous definition of basis with a continuous set of indices and consequently for a rigorous definition of position and momentum basis, see. For a rigorous statement of the expansion of an S-diagonalizable operator, or observable, in its eigenbasis or in another basis, see.
Banach spaces are a different generalization of Hilbert spaces. In a Banach space B, the vectors may be notated by kets and the continuous linear functionals by bras. Over any vector space without topology, we may also notate the vectors by kets and the linear functionals by bras. In these more general contexts, the bracket does not have the meaning of an inner product, because the Riesz representation theorem does not apply.
Usage in quantum mechanics
The mathematical structure of quantum mechanics is based in large part on linear algebra:
Since virtually every calculation in quantum mechanics involves vectors and linear operators, it can involve, and often does involve, bra-ket notation. A few examples follow:
Spinless position–space wave function
The Hilbert space of a spin-0 point particle is spanned by a "position basis" { |r⟩ }, where the label r extends over the set of all points in position space. Since there are an uncountably infinite number of vector components in the basis, this is an uncountably infinite-dimensional Hilbert space. The dimensions of the Hilbert space (usually infinite) and position space (usually 1, 2 or 3) are not to be conflated.
Starting from any ket |Ψ⟩ in this Hilbert space, we can define a complex scalar function of r, known as a wavefunction:
On the left side, Ψ(r) is a function mapping any point in space to a complex number; on the right side, |Ψ⟩ = ∫ d3r Ψ(r) |r⟩ is a ket.
It is then customary to define linear operators acting on wavefunctions in terms of linear operators acting on kets, by
For instance, the momentum operator p has the following form,
One occasionally encounters an expression as
though this is something of an abuse of notation. The differential operator must be understood to be an abstract operator, acting on kets, that has the effect of differentiating wavefunctions once the expression is projected into the position basis,
even though, in the momentum basis, the operator amounts to a mere multiplication operator (by iħp).
Overlap of states
In quantum mechanics the expression
Changing basis for a spin-1/2 particle
A stationary spin-½ particle has a two-dimensional Hilbert space. One orthonormal basis is:
where
Since these are a basis, any quantum state of the particle can be expressed as a linear combination (i.e., quantum superposition) of these two states:
where aψ, bψ are complex numbers.
A different basis for the same Hilbert space is:
defined in terms of Sx rather than Sz.
Again, any state of the particle can be expressed as a linear combination of these two:
In vector form, you might write
depending on which basis you are using. In other words, the "coordinates" of a vector depend on the basis used.
There is a mathematical relationship between aψ, bψ, cψ, dψ; see change of basis.
Misleading uses
There are a few conventions and abuses of notation that are generally accepted by the physics community, but which might confuse the non-initiated.
It is common to use the same symbol for labels and constants in the same equation. For example, α̂ |α⟩ = α|α⟩, where the symbol α is used simultaneously as the name of the operator α̂, its eigenvector |α⟩ and the associated eigenvalue α.
Something similar occurs in component notation of vectors. While Ψ (uppercase) is traditionally associated with wavefunctions, ψ (lowercase) may be used to denote a label, a wave function or complex constant in the same context, usually differentiated only by a subscript.
The main abuses are including operations inside the vector labels. This is usually done for a fast notation of scaling vectors. E.g. if the vector |α⟩ is scaled by √2, it might be denoted by |α/√2⟩, which makes no sense since α is a label, not a function or a number, so you can't perform operations on it.
This is especially common when denoting vectors as tensor products, where part of the labels are moved outside the designed slot, e.g. |α⟩ = |α/√21⟩ ⊗ |α/√22⟩. Here part of the labeling that should state that all three vectors are different was moved outside the kets, as subscripts 1 and 2. And a further abuse occurs, since α is meant to refer to the norm of the first vector—which is a label denoting a value.
Linear operators acting on kets
A linear operator is a map that inputs a ket and outputs a ket. (In order to be called "linear", it is required to have certain properties.) In other words, if A is a linear operator and |ψ⟩ is a ket, then A|ψ⟩ is another ket.
In an N-dimensional Hilbert space, |ψ⟩ can be written as an N×1 column vector, and then A is an N×N matrix with complex entries. The ket A|ψ⟩ can be computed by normal matrix multiplication.
Linear operators are ubiquitous in the theory of quantum mechanics. For example, observable physical quantities are represented by self-adjoint operators, such as energy or momentum, whereas transformative processes are represented by unitary linear operators such as rotation or the progression of time.
Linear operators acting on bras
Operators can also be viewed as acting on bras from the right hand side. Specifically, if A is a linear operator and ⟨φ| is a bra, then ⟨φ|A is another bra defined by the rule
(in other words, a function composition). This expression is commonly written as (cf. energy inner product)
In an N-dimensional Hilbert space, ⟨φ| can be written as a 1×N row vector, and A (as in the previous section) is an N×N matrix. Then the bra ⟨φ|A can be computed by normal matrix multiplication.
If the same state vector appears on both bra and ket side,
then this expression gives the expectation value, or mean or average value, of the observable represented by operator A for the physical system in the state |ψ⟩.
Outer products
A convenient way to define linear operators on Hilbert space H is given by the outer product: if ⟨φ| is a bra and |ψ⟩ is a ket, the outer product
denotes the rank-one operator with the rule
For a finite-dimensional vector space, the outer product can be understood as simple matrix multiplication:
The outer product is an N×N matrix, as expected for a linear operator.
One of the uses of the outer product is to construct projection operators. Given a ket |ψ⟩ of norm 1, the orthogonal projection onto the subspace spanned by |ψ⟩ is
Hermitian conjugate operator
Just as kets and bras can be transformed into each other (making |ψ⟩ into ⟨ψ|), the element from the dual space corresponding to A|ψ⟩ is ⟨ψ|A†, where A† denotes the Hermitian conjugate (or adjoint) of the operator A. In other words,
If A is expressed as an N×N matrix, then A† is its conjugate transpose.
Self-adjoint operators, where A = A†, play an important role in quantum mechanics; for example, an observable is always described by a self-adjoint operator. If A is a self-adjoint operator, then ⟨ψ|A|ψ⟩ is always a real number (not complex). This implies that expectation values of observables are real.
Properties
bra-ket notation was designed to facilitate the formal manipulation of linear-algebraic expressions. Some of the properties that allow this manipulation are listed herein. In what follows, c1 and c2 denote arbitrary complex numbers, c∗ denotes the complex conjugate of c, A and B denote arbitrary linear operators, and these properties are to hold for any choice of bras and kets.
Linearity
Associativity
Given any expression involving complex numbers, bras, kets, inner products, outer products, and/or linear operators (but not addition), written in bra-ket notation, the parenthetical groupings do not matter (i.e., the associative property holds). For example:
and so forth. The expressions on the right (with no parentheses whatsoever) are allowed to be written unambiguously because of the equalities on the left. Note that the associative property does not hold for expressions that include non-linear operators, such as the antilinear time reversal operator in physics.
Hermitian conjugation
bra-ket notation makes it particularly easy to compute the Hermitian conjugate (also called dagger, and denoted †) of expressions. The formal rules are:
These rules are sufficient to formally write the Hermitian conjugate of any such expression; some examples are as follows:
Composite bras and kets
Two Hilbert spaces V and W may form a third space V ⊗ W by a tensor product. In quantum mechanics, this is used for describing composite systems. If a system is composed of two subsystems described in V and W respectively, then the Hilbert space of the entire system is the tensor product of the two spaces. (The exception to this is if the subsystems are actually identical particles. In that case, the situation is a little more complicated.)
If |ψ⟩ is a ket in V and |φ⟩ is a ket in W, the direct product of the two kets is a ket in V ⊗ W. This is written in various notations:
See quantum entanglement and the EPR paradox for applications of this product.
The unit operator
Consider a complete orthonormal system (basis),
with
From the commutativity of kets with (complex) scalars now follows that
must be the identity operator, which sends each vector to itself. This can be inserted in any expression without affecting its value, for example
where, in the last identity, the Einstein summation convention has been used.
In quantum mechanics, it often occurs that little or no information about the inner product
For more information, see Resolution of the identity, 1 = ∫ dx |x⟩⟨x| = ∫ dp |p⟩⟨p|, where |p⟩ = ∫ dx eixp/ħ|x⟩/√2πħ; since ⟨x′|x⟩ = δ(x − x′), plane waves follow, ⟨x|p⟩ = exp(ixp/ħ)/√2πħ.
Notation used by mathematicians
The object physicists are considering when using the "bra-ket" notation is a Hilbert space (a complete inner product space).
Let
Let
where
One ignores the parentheses and removes the double bars. Some properties of this notation are convenient since we are dealing with linear operators and composition acts like a ring multiplication.
Moreover, mathematicians usually write the dual entity not at the first place, as the physicists do, but at the second one, and they don't use the *-symbol, but an overline (which the physicists reserve for averages and Dirac conjugation) to denote conjugate-complex numbers, i.e. for scalar products mathematicians usually write
whereas physicists would write for the same quantity