Harman Patil (Editor)

Balz–Schiemann reaction

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Reaction type
  
Substitution reaction

Named after
  
Günther Balz Günther Schiemann

Organic Chemistry Portal
  
balz-schiemann-reaction

The Schiemann reaction (also called the Balz–Schiemann reaction) is a chemical reaction in which anilines (1) are transformed to aryl fluorides (3) via diazonium fluoroborates (2). Named after the German chemists Günther Schiemann and Günther Balz, this reaction is the preferred route to fluorobenzene and some related derivatives, including 4-fluorobenzoic acid.

Ar NH 2 1 + HBF 4 HNO 2 Ar N + N 2 diazonium   fluoroborates + BF 4 Δ Ar F 3 aryl   fluoride + BF 3 + N 2

The reaction is similar to the Sandmeyer reaction, which converts diazonium salts to other aryl halides.

References

Balz–Schiemann reaction Wikipedia