Aluminium in Africa originates primarily in Guinea, Mozambique and Ghana. Guinea is by far the biggest producer in Africa, and is a world leader in aluminium and bauxite production; see "World bauxite mine production, reserves, and reserve base" at the bauxite article.
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There are many companies involved in the aluminium trade in Africa. Principal mine and smelter operators include:
Cameroon
Egypt
www.egyptalum.com.e.g. Nagehammadi factory of aluminium
Ghana
Guinea
Mozambique
South Africa
References
Aluminium in Africa Wikipedia(Text) CC BY-SA