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Aluminium dodecaboride

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Formula
  
AlB12

Density
  
2.56 g/cm³

Molar mass
  
156.714 g/mol

Appearance
  
Yellow to black solid

Aluminium dodecaboride (AlB12) is a chemical compound made from the metal aluminium and the non-metal boron. It is one of two chemical compounds that are commonly called aluminium boride; the other is aluminium diboride, AlB2.

Contents

Properties

There are two crystalline forms, α-AlB12, and γ-AlB12. Both forms are very similar and consist of a framework with three-dimensional networks of B12 and B20 units. The phase β-AlB12 is now believed to be the ternary boride C2Al3B48.

Preparation

The β-form can be prepared by the reaction of boron(III) oxide with sulfur and aluminum, then adding carbon to the mixture.

Uses

AlB12 is used as a grinding compound to replace diamond or corundum.

References

Aluminium dodecaboride Wikipedia


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