Rahul Sharma (Editor)

Acetone oxime

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Solubility in water
  
330 kg/m³

Acetone oxime httpsuploadwikimediaorgwikipediacommonsthu

Appearance
  
White needle like crystals

Acetone oxime (acetoxime) is the organic compound with the formula (CH3)2CNOH. It is the simplest example of a ketoxime. It is a white crystalline solid that is soluble in water, ethanol, ether, chloroform, and ligroin. It is used as a reagent in organic synthesis.

Contents

Preparation

Acetone oxime is synthesized by the condensation of acetone and hydroxylamine in the presence of HCl:

(CH3)2CO + H2NOH → (CH3)2CNOH + H2O

It can also be generated via ammoxidation of acetone in the presence of hydrogen peroxide.

Uses

Acetone oxime is an excellent corrosion inhibitor (deoxidant) with lower toxicity and greater stability compared to the common agent hydrazine. It is also useful in the determination of ketones, cobalt, and in organic synthesis.

References

Acetone oxime Wikipedia