| 7–5, 2–6, [10–7]|
| Klaudia Jans-Ignacik
Liezel Huber and Lisa Raymond were the defending champions but lost to Nadia Petrova and Katarina Srebotnik in the semifinals 6–4, 6–4.
Klaudia Jans-Ignacik and Kristina Mladenovic won the title by defeating Nadia Petrova and Katarina Srebotnik 7–5, 2–6, [10–7] in the final.
2012 Rogers Cup – Women's Doubles Wikipedia
The top four seeds receive a bye into the second round.