| 6–3, 7–6|
| Andrei Pavel
Mark Knowles and Daniel Nestor were the defending champions, but lost in the quarterfinals this year.
Andrei Pavel and Alexander Waske won in the final 6–3, 7–6(7–1), against Rafael Nadal and Bartolomé Salvá-Vidal.
2007 Torneo Godó – Doubles Wikipedia
All seeds receive a bye into the second round.