Volpe means "fox" in Italian. As a surname, it may refer to:
Alessandro Volpe, Italian footballer
Francesco Volpe, Italian footballer
Fiona Volpe, Bond villain in Thunderball
John A. Volpe (1906–1994), former Governor of Massachusetts and U.S. Secretary of Transportation
Joe Volpe (born 1947), Canadian politician
Joseph Volpe (opera manager) (born 1940), general manager of the Metropolitan Opera in New York
Justin Volpe, New York City police officer convicted and imprisoned for assaulting Abner Louima
Michael Volpe (born 1987), Michael Volpe known as Clams Casino
Robert Volpe (1942–2006), painter and New York City police detective, specializing in art theft