Valcárcel is a surname. Notable people with the surname include:
Alejandro Rodríguez de Valcárcel (1917–1976), Francoist Spanish politicianAntonio "Kitin" Munoz Valcarcel (born 1958), Spanish navigator, scientist and sociological explorerAurelio Valcárcel Carroll, television producer and director associated with the Telemundo television networkCarlos Valcárcel (born 1981), boxer from Puerto Rico, competitor at the 2000 Summer Olympics in Sydney, AustraliaEleazar Huerta Valcárcel (1903–1974), Spanish lawyer and politicianGisela Valcárcel (born 1963), Peruvian television hostess, actress and businesswomanRamón Luis Valcárcel Siso (born 1954), Spanish politician, president of the Autonomous Community of the Region of Murcia from 1995