Rahul Sharma (Editor)

Swain equation

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The Swain equation relates the kinetic isotope effect for the protium/tritium combination with that of the protium/deuterium combination according to:

k H k T = ( k H k D ) 1.442

where kH,D,T are the reaction rate constants for the protonated, deuterated and tritiated reactants respectively.

References

Swain equation Wikipedia


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