Formula C5H5NSO3 Appearance white solid | Molar mass 159.16 g/mol Pubchem 168533 | |
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Sulfur trioxide pyridine complex is the compound with the formula C5H5NSO3. It is a colourless solid that dissolves in polar organic solvents. It is the adduct formed from the Lewis base pyridine and the Lewis acid sulfur trioxide. The compound is mainly used as a source of sulfur trioxide, for example in the synthesis of sulfate esters from alcohols:
ROH + C5H5NSO3 → [C5H5NH]+[ROSO3]−
This is useful for sulfonylation reactions, especially in the sulfonylation of furans. It is also an activating electrophile in a Parikh-Doering oxidation.
References
Sulfur trioxide pyridine complex Wikipedia(Text) CC BY-SA