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Stimulated Raman adiabatic passage

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Stimulated Raman adiabatic passage via the ionization continuum in helium:  Experiment and theory - ScienceDirect

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Surface enhanced Raman spectroscopy, Transmission Raman spectroscopy, Spatially offset Raman spectroscopy

The Stimulated Raman adiabatic passage (STIRAP) process permits transfer of a population between two applicable quantum states via at least two coherent electromagnetic (light) pulses. These light pulses drive the transitions of the three level Ʌ atom or multilevel system. The process is a form of state-to-state coherent control.

Population transfer in three level Ʌ atom

Consider the description of three level Ʌ atom having ground states | g 1 and | g 2 (for simplicity suppose that the energies of the ground states are the same) and excited state | e . Suppose in the beginning the total population is in the ground state | g 1 . Here the logic for transformation of the population from ground state | g 1 to | g 2 is that initially the unpopulated states | g 2 and | e couple, afterward superposition of state | g 2 and | e couple to the state | g 1 . Thereby a state is formed that permits the transformation of the population into state | g 2 without populating the excited state | e . This process of transforming the population without populating the excited state is called the stimulated Raman adiabatic passage.

References

Stimulated Raman adiabatic passage Wikipedia