Puneet Varma (Editor)

Rodrigues equation

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The Rodrigues equation is an equation used in chromatography to describe the efficiency of a bed of permeable (large-pore) particles. It is thus an extension of Van Deemter's equation. It was developed by Alirio E. Rodrigues et al..

Equation

The equation is:

H E T P = A + B u + C f ( λ ) u

Where

  • HETP is the height equivalent to a theoretical plate
  • A = Eddy diffusion
  • B = Longitudinal diffusion
  • C = Resistance to mass transfer
  • u = Flow rate
  • f ( λ ) = 3 λ [ 1 t a n h ( λ ) 1 λ ]
  • λ = Intraparticular Péclet number
  • References

    Rodrigues equation Wikipedia