In the Newman–Penrose (NP) formalism of general relativity, independent components of the Ricci tensors of a four-dimensional spacetime are encoded into seven (or ten) Ricci scalars which consist of three real scalars                     {                  Φ                      00                          ,                  Φ                      11                          ,                  Φ                      22                          }                , three (or six) complex scalars                     {                  Φ                      01                          =                                            Φ              ¯                                            10                                  ,                  Φ                      02                          =                                            Φ              ¯                                            20                                  ,                  Φ                      12                          =                                            Φ              ¯                                            21                          }                 and the NP curvature scalar                     Λ                . Physically, Ricci-NP scalars are related with the energy–momentum distribution of the spacetime due to Einstein's field equation.
Given a complex null tetrad                     {                  l                      a                          ,                  n                      a                          ,                  m                      a                          ,                                                            m                ¯                                                          a                          }                 and with the convention                     {        (        −        ,        +        ,        +        ,        +        )        ;                  l                      a                                    n                      a                          =        −        1                ,                  m                      a                                                                              m                ¯                                                          a                          =        1        }                , the Ricci-NP scalars are defined by (where overline means complex conjugate)
                              Φ                      00                          :=                              1            2                                    R                      a            b                                    l                      a                                    l                      b                                  ,                          Φ                      11                          :=                              1            4                                    R                      a            b                          (                          l                      a                                    n                      b                          +                  m                      a                                                                              m                ¯                                                          b                          )                ,                          Φ                      22                          :=                              1            2                                    R                      a            b                                    n                      a                                    n                      b                                  ,                Λ        :=                              R            24                                  ;                
                              Φ                      01                          :=                              1            2                                    R                      a            b                                    l                      a                                    m                      b                                  ,                                  Φ                      10                          :=                              1            2                                    R                      a            b                                    l                      a                                                                              m                ¯                                                          b                          =                                            Φ              ¯                                            01                                  ,                
                              Φ                      02                          :=                              1            2                                    R                      a            b                                    m                      a                                    m                      b                                  ,                          Φ                      20                          :=                              1            2                                    R                      a            b                                                                              m                ¯                                                          a                                                                              m                ¯                                                          b                          =                                            Φ              ¯                                            02                                  ,                
                              Φ                      12                          :=                              1            2                                    R                      a            b                                    m                      a                                    n                      b                                  ,                                  Φ                      21                          :=                              1            2                                    R                      a            b                                                                              m                ¯                                                          a                                    n                      b                          =                                            Φ              ¯                                            12                                  .                
Remark I: In these definitions,                               R                      a            b                                   could be replaced by its trace-free part                               Q                      a            b                          =                  R                      a            b                          −                              1            4                                    g                      a            b                          R                 or by the Einstein tensor                               G                      a            b                          =                  R                      a            b                          −                              1            2                                    g                      a            b                          R                 because of the normalization (i.e. inner product) relations that
                              l                      a                                    l                      a                          =                  n                      a                                    n                      a                          =                  m                      a                                    m                      a                          =                                                            m                ¯                                                          a                                                                              m                ¯                                                          a                          =        0                ,                                              l                      a                                    m                      a                          =                  l                      a                                                                              m                ¯                                                          a                          =                  n                      a                                    m                      a                          =                  n                      a                                                                              m                ¯                                                          a                          =        0                .                Remark II: Specifically for electrovacuum, we have                     Λ        =        0                , thus
                    24        Λ                =        0        =                          R                      a            b                                    g                      a            b                                  =                          R                      a            b                                                (                          −        2                  l                      a                                    n                      b                          +        2                  m                      a                                                                              m                ¯                                                          b                                                )                                  ⇒                          R                      a            b                                    l                      a                                    n                      b                                  =                          R                      a            b                                    m                      a                                                                              m                ¯                                                          b                                  ,                
and therefore                               Φ                      11                                   is reduced to
                              Φ                      11                          :=                              1            4                                    R                      a            b                          (                          l                      a                                    n                      b                          +                  m                      a                                                                              m                ¯                                                          b                          )        =                              1            2                                    R                      a            b                                    l                      a                                    n                      b                          =                              1            2                                    R                      a            b                                    m                      a                                                                              m                ¯                                                          a                                  .                
Remark III: If one adopts the convention                     {        (        +        ,        −        ,        −        ,        −        )        ;                  l                      a                                    n                      a                          =        1                ,                  m                      a                                                                              m                ¯                                                          a                          =        −        1        }                , the definitions of                               Φ                      i            j                                   should take the opposite values; that is to say,                               Φ                      i            j                          ↦        −                  Φ                      i            j                                   after the signature transition.
According to the definitions above, one should find out the Ricci tensors before calculating the Ricci-NP scalars via contractions with the corresponding tetrad vectors. However, this method fails to fully reflect the spirit of Newman–Penrose formalism and alternatively, one could compute the spin coefficients and then derive the Ricci-NP scalars                               Φ                      i            j                                   via relevant NP field equations that
                              Φ                      00                          =        D        ρ        −                                            δ              ¯                                      κ        −        (                  ρ                      2                          +        σ                                            σ              ¯                                      )        −        (        ε        +                                            ε              ¯                                      )        ρ        +                                            κ              ¯                                      τ        +        κ        (        3        α        +                                            β              ¯                                      −        π        )                ,                                              Φ                      10                          =        D        α        −                                            δ              ¯                                      ε        −        (        ρ        +                                            ε              ¯                                      −        2        ε        )        α        −        β                                            σ              ¯                                      +                                            β              ¯                                      ε        +        κ        λ        +                                            κ              ¯                                      γ        −        (        ε        +        ρ        )        π                ,                                              Φ                      02                          =        δ        τ        −        Δ        σ        −        (        μ        σ        +                                            λ              ¯                                      ρ        )        −        (        τ        +        β        −                                            α              ¯                                      )        τ        +        (        3        γ        −                                            γ              ¯                                      )        σ        +        κ                                            ν              ¯                                              ,                                              Φ                      20                          =        D        λ        −                                            δ              ¯                                      π        −        (        ρ        λ        +                                            σ              ¯                                      μ        )        −                  π                      2                          −        (        α        −                                            β              ¯                                      )        π        +        ν                                            κ              ¯                                      +        (        3        ε        −                                            ε              ¯                                      )        λ                ,                                              Φ                      12                          =        δ        γ        −        Δ        β        −        (        τ        −                                            α              ¯                                      −        β        )        γ        −        μ        τ        +        σ        ν        +        ε                                            ν              ¯                                      +        (        γ        −                                            γ              ¯                                      −        μ        )        β        −        α                                            λ              ¯                                              ,                                              Φ                      22                          =        δ        ν        −        Δ        μ        −        (                  μ                      2                          +        λ                                            λ              ¯                                      )        −        (        γ        +                                            γ              ¯                                      )        μ        +                                            ν              ¯                                      π        −        (        τ        −        3        β        −                                            α              ¯                                      )        ν                ,                                    2                  Φ                      11                          =        D        γ        −        Δ        ε        +        δ        α        −                                            δ              ¯                                      β        −        (        τ        +                                            π              ¯                                      )        α        −        α                                            α              ¯                                      −        (                                            τ              ¯                                      +        π        )        β        −        β                                            β              ¯                                      +        2        α        β        +        (        ε        +                                            ε              ¯                                      )        γ        −        (        ρ        −                                            ρ              ¯                                      )        γ        +        (        γ        +                                            γ              ¯                                      )        ε        −        (        μ        −                                            μ              ¯                                      )        ε        −        τ        π        +        ν        κ        −        (        μ        ρ        −        λ        σ        )                ,                while the NP curvature scalar                     Λ                 could be directly and easily calculated via                     Λ        =                              R            24                                   with                     R                 being the ordinary scalar curvature of the spacetime metric                               g                      a            b                          =        −                  l                      a                                    n                      b                          −                  n                      a                                    l                      b                          +                  m                      a                                                                              m                ¯                                                          b                          +                                                            m                ¯                                                          a                                    m                      b                                  .
According to the definitions of Ricci-NP scalars                               Φ                      i            j                                   above and the fact that                               R                      a            b                                   could be replaced by                               G                      a            b                                   in the definitions,                               Φ                      i            j                                   are related with the energy–momentum distribution due to Einstein's field equations                               G                      a            b                          =        8        π                  T                      a            b                                  . In the simplest situation, i.e. vacuum spacetime in the absence of matter fields with                               T                      a            b                          =        0                , we will have                               Φ                      i            j                          =        0                . Moreover, for electromagnetic field, in addition to the aforementioned definitions,                               Φ                      i            j                                   could be determined more specifically by
                              Φ                      i            j                          =                2                          ϕ                      i                                                                      ϕ              ¯                                            j                                  ,                (        i        ,        j        ∈        {        0        ,        1        ,        2        }        )                ,                
where                               ϕ                      i                                   denote the three complex Maxwell-NP scalars which encode the six independent components of the Faraday-Maxwell 2-form                               F                      a            b                                   (i.e. the electromagnetic field strength tensor)
                              ϕ                      0                          :=        −                  F                      a            b                                    l                      a                                    m                      b                                  ,                          ϕ                      1                          :=        −                              1            2                                    F                      a            b                                                (                                    l                      a                                    n                      a                          −                  m                      a                                                                              m                ¯                                                          b                                                )                                  ,                          ϕ                      2                          :=                  F                      a            b                                    n                      a                                                                              m                ¯                                                          b                                  .                
Remark: The equation                               Φ                      i            j                          =        2                          ϕ                      i                                                                      ϕ              ¯                                            j                                   for electromagnetic field is however not necessarily valid for other kinds of matter fields. For example, in the case of Yang–Mills fields there will be                               Φ                      i            j                          =                          Tr                        (                  ϝ                      i                                                                                      ϝ                ¯                                                          j                          )                 where                               ϝ                      i                          (        i        ∈        {        0        ,        1        ,        2        }        )                 are Yang–Mills-NP scalars.