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Reichardt's dye

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Reichardt's dye Reichardt39s dye Wikipedia

Reichardt's dye (Betaine 30) is an organic dye belonging to the class of azomerocyanine betaines. This dye is notable for its solvatochromic properties, meaning it changes color depending on the solvent in which it is dissolved. It has one of the largest solvachromic effects ever observed, with color varying across the entire visible spectrum. As a result, it gives striking visual results for chemical demonstrations.

Reichardt's dye httpsuploadwikimediaorgwikipediacommonsthu

This chemical is named for Christian Reichardt, who developed it when working as a doctoral student in the lab of Karl Dimroth. It is thus also sometimes called Dimroth–Reichardt dye. The names also sometimes refer to some close chemical analogs, in particular, the one having para substituted tert-butyl groups on the phenyl rings.

Reichardt's dye Mesostructured SBA3 silica containing Reichardt39s dye as an optical

Synthesis

A newer synthesis is:

Reichardt's dye Reichardt39s dye CAS 10081397 SCBT

2,6-Diphenylphenol is nitrated with diluted nitric acid to 4-Nitro-2,6-diphenylphenol and subsequently reduced with sodium dithionite to the amine. This is reacted in presence of sodium acetate in ethanol with 2,4,6-Triphenylpyryliumhydrogensulfate to the hydrogensulfat of the dye and the betaine is formed by adding sodium hydroxide.

Reichardt's dye Behavior of the solvatochromic probes Reichardt39s dye pyrene

References

Reichardt's dye Wikipedia