Girish Mahajan (Editor)

Pentagonal planar molecular geometry

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Examples
  
XeF5

Coordination number
  
5

Steric number
  
7

Bond angle(s)
  
72°, 144°

Pentagonal planar molecular geometry

In chemistry, the pentagonal planar molecular geometry describes the shape of compounds where five atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a pentagon.

Examples

The only two pentagonal planar species known are the isoelectronic (nine valence electrons) ions XeF
5
and IF2−
5
. Both are derived from the pentagonal bipyramid with two lone pairs occupying the apical positions and the five fluorine atoms all equatorial.

References

Pentagonal planar molecular geometry Wikipedia