An off-centered rhyme is a rhyme scheme characterized by placing rhyming words or syllables in unexpected places in a given line. This is sometimes called a misplaced-rhyme scheme, or a Spoken Word rhyme style.
Here's an example from a recording artist from De La Soul:
Playin waitor, with the data servin' your earswith information due to confirmation of the nation's mostwicked ways of livin, like them glassy eyed beansInhale to smoke the fiends, while bangin' a tapeRated at the high point of the massRippin' MC's at the top of a class, occasionallyrippin' some sucker's face, or some suckable ass from a girlIt's a big brother beat for the wide wide worldThis is a common rhyme scheme found in the Spoken Word form of poetry. This can be found in Hip-hop as well, but it is not as common in Hip-hop as it is in Spoken Word.
References
Off-centered rhyme Wikipedia(Text) CC BY-SA