Libero is the given name of:
Libero Ajello (1916–2004), mycologist (see List of mycologists)
Libero Andreotti (1875–1933), Italian sculptor, illustrator and ceramics artist
Líbero Badaró (1798–1830), Italian Brazilian physician, botanist, journalist and politician who was assassinated
Libero Grassi (1924–1991), Italian clothing manufacturer murdered by the Mafia
Libero Liberati (1926–1962), Italian motorcycle racer
Libero De Luca (1913–1997), Italian lyric tenor
Líbero Parri (born 1982), Spanish footballer
Libero Tresoldi (1921–2009), Italian Bishop of Crema