Kalpana Kalpana (Editor)

Khomyakovite

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Dana classification
  
64.1.2.5

Crystal system
  
Trigonal

Category
  
Silicate mineral, Cyclosilicate

Formula(repeating unit)
  
Na12Sr3Ca6Fe3Zr3W(Si25O73)(O,OH,H2O)3(OH,Cl)2 (original form)

Strunz classification
  
9.CO.10 (10 ed)8/E.23-30 (8 ed)

Crystal class
  
Ditrigonal pyramidal (3m)H-M symbol: (3m)

Khomyakovite is an exceedingly rare mineral of the eudialyte group, with formula Na12Sr3Ca6Fe3Zr3WSi(Si9O27)2(Si3O9)2O(O,OH,H2O)3(OH,Cl)2. The original formula was extended to show the presence of both the cyclic silicate groups and M4-site silicon, according to the nomenclature of the eudialyte group. Some niobium substitutes for tungsten in khomyakovite. Khomyakovite is an iron-analogue of manganokhomyakovite, the second mineral being a bit more common. The two minerals are the only group representatives, beside taseqite, with species-defining strontium, although many other members display stronium diadochy. Khomyakovite is the third eudialyte-group mineral with essential tungsten (after johnsenite-(Ce) and manganokhomyakovite).

Occurrence and association

Khomyakovite, manganokhomyakovite, johnsenite-(Ce) and oneillite are four eudialyte-group minerals with type locality in Mont Saint-Hilaire, Quebec, Canada. Khomyakovite itself is associated with analcime, annite, natrolite, titanite, calcite, and pyrite.

References

Khomyakovite Wikipedia


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