Supriya Ghosh (Editor)

Isotopes of chromium

Updated on
Edit
Like
Comment
Share on FacebookTweet on TwitterShare on LinkedInShare on Reddit

Naturally occurring chromium (Cr) is composed of four stable isotopes; 50Cr, 52Cr, 53Cr, and 54Cr with 52Cr being the most abundant (83.789% natural abundance). 50Cr is suspected of decaying by β+β+ to 50Ti with a half-life of (more than) 1.8x1017 years. Twenty-two radioisotopes, all of which are entirely synthetic, have been characterized with the most stable being 51Cr with a half-life of 27.7 days. All of the remaining radioactive isotopes have half-lives that are less than 24 hours and the majority of these have half-lives that are less than 1 minute, the least stable being 66Cr with a half-life of 10 milliseconds. This element also has 2 meta states, 45Crm, the more stable one, and 59Crm, the least stable isotope or isomer.

53Cr is the radiogenic decay product of 53Mn. Chromium isotopic contents are typically combined with manganese isotopic contents and have found application in isotope geology. Mn-Cr isotope ratios reinforce the evidence from 26Al and 107Pd for the early history of the solar system. Variations in 53Cr/52Cr and Mn/Cr ratios from several meteorites indicate an initial 53Mn/55Mn ratio that suggests Mn-Cr isotope systematics must result from in-situ decay of 53Mn in differentiated planetary bodies. Hence 53Cr provides additional evidence for nucleosynthetic processes immediately before coalescence of the solar system. The same isotope is preferentially involved in certain leaching reactions, thereby allowing its abundance in seawater sediments to be used as a proxy for atmospheric oxygen concentrations.

The isotopes of chromium range from 42Cr to 67Cr. The primary decay mode before the most abundant stable isotope, 52Cr, is electron capture and the primary mode after is beta decay.

Relative atomic mass: 51.9961(6)

Notes

  • Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
  • Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC, which use expanded uncertainties.
  • Nuclide masses are given by IUPAP Commission on Symbols, Units, Nomenclature, Atomic Masses and Fundamental Constants (SUNAMCO)
  • Isotope abundances are given by IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
  • References

    Isotopes of chromium Wikipedia