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Hexaborane(12)

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colorless gas

Hexaborane(12)

Hexaborane(12) is an inorganic compound with the formula B6H12. It is an obscure member of the boranes. It is a colorless liquid that, like most boron hydrides, is readily hydrolyzed and flammable.

The molecular structure conforms to C2 symmetry group. With the formula BnHn+6, it is classified as an arachno cluster. As such the boron positions match six of the boron positions in the closo-B8H2−
8
.

Preparation

It is typically prepared by the cluster expansion method from B5H
8
, the conjugate base of pentaborane-9:

LiB5H8 + 1/2 B2H6 → LiB6H11 LiB6H11 + HCl → B6H12 + LiCl

References

Hexaborane(12) Wikipedia