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Hemovanadin is a pale green vanabin protein found in the blood cells, called vanadocytes, of ascidians (sea squirts) and other organisms. It is one of the few known vanadium-containing proteins.
The German chemist Martin Henze first detected vanadium in ascidians (sea squirts) in 1911. Unlike hemocyanin and hemoglobin, hemovanadin is not an oxygen carrier.
References
Hemovanadin Wikipedia(Text) CC BY-SA