Samiksha Jaiswal (Editor)

Friedel's law

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Friedel's law, named after Georges Friedel, is a property of Fourier transforms of real functions.

Given a real function f ( x ) , its Fourier transform

F ( k ) = + f ( x ) e i k x d x

has the following properties.

  • F ( k ) = F ( k )
  • where F is the complex conjugate of F .

    Centrosymmetric points ( k , k ) are called Friedel's pairs.

    The squared amplitude ( | F | 2 ) is centrosymmetric:

  • | F ( k ) | 2 = | F ( k ) | 2
  • The phase ϕ of F is antisymmetric:

  • ϕ ( k ) = ϕ ( k ) .
  • Friedel's law is used in X-ray diffraction, crystallography and scattering from real potential within the Born approximation. Note that a twin operation (a.k.a. Opération de maclage) is equivalent to an inversion centre and the intensities from the individuals are equivalent under Friedel's law.

    References

    Friedel's law Wikipedia