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Cycloprop-2-ene carboxylic acid is a mycotoxin found in some mushrooms such as Russula subnigricans and Tricholoma equestre.
When ingested, the molecule is known to cause rhabdomyolysis.
In mice, the molecule is lethal at 2.5 mg/kg of body mass (oral route) and poisoning is indicated by an increase in serum creatine phosphokinase activity. Polymerization via the ene reaction abolishes toxicity.
References
Cycloprop-2-ene carboxylic acid Wikipedia(Text) CC BY-SA